MXene@聚多巴胺的制备、性能和应用

doi:10.19677/j.issn.1004-7964.2024.01.003

皮革科学与工程 ›› 2024, Vol. 34 ›› Issue (1): 18-23.doi: 10.19677/j.issn.1004-7964.2024.01.003

MXene@聚多巴胺的制备、性能和应用

周建华^1,2,*, 晏亚飞^1,2, 周梦园^1,2

1.陕西科技大学轻工科学与工程学院,陕西西安 710021;
2.轻化工程国家级实验教学示范中心（陕西科技大学）,陕西西安 710021

收稿日期:2023-05-25 修回日期:2023-07-21 接受日期:2023-08-13 出版日期:2024-02-01 上线日期:2024-01-08
通讯作者: *
作者简介:周建华(1973-),女,博士,教授,主要从事功能皮革化学品的合成及应用研究。E-mail:zhoujianh@21cn.com。
基金资助:
国家自然科学基金（21978162）; 咸阳市重点研发计划（2021ZDYF-GY-0037）; 西安市科技计划项目（22GXFW0003）

Preparation, Properties and Application of MXene@Polydopamine

ZHOU Jianhua^1,2,*, YAN Yafei^1,2, ZHOU Mengyuan^1,2

1. College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science & Technology, Xi'an 710021, China;
2. National Demonstration Center for Experimental Light Chemistry Engineering Education (Shaanxi University of Science & Technology), Xi'an 710021, China

Received:2023-05-25 Revised:2023-07-21 Accepted:2023-08-13 Online:2024-02-01 Published:2024-01-08

摘要/Abstract

摘要： 将光热转换材料聚多巴胺包覆的MXene（MXene@PDA）引入胶原气凝胶,来提高其光热转换能力,扩大其在低温防护领域的应用范围。采用化学刻蚀和原位锂离子插层法制备了MXene,然后利用多巴胺（DA）在MXene表面发生氧化自聚合反应,得到了MXene@PDA,探讨了DA用量对MXene@PDA性能的影响。利用透射电子显微镜、扫描电子显微镜、X-射线衍射和紫外-可见-近红外光谱对MXene@PDA的结构和性能进行了测试和表征。结果表明PDA被成功包覆在MXene薄片上,提高了MXene的环境稳定性。当MXene与DA的质量比为100∶6时,制得的MXene@PDA光吸收性能最佳。在100 mW/cm²氙灯照射下,MXene@PDA改性胶原气凝胶的温度高达54.8 ℃,相比于胶原气凝胶提升了17.9 ℃,并且在多次光热循环实验中最高温度都在54.8 ℃左右,表现出优异的光热转换性能和循环稳定性。

关键词: MXene, 聚多巴胺, 光热转换, 胶原, 气凝胶

Abstract: Polydopamine-coated MXene (MXene@PDA), a photothermal conversion material, was introduced into collagen aerogel to improve its photothermal conversion ability and expand its application in the field of low temperature protection. MXene was prepared by chemical etching and in situ lithium-ion intercalation, and then the oxidative self-polymerization reaction of dopamine (DA) on the surface of MXene was utilized to obtain MXene@PDA. Moreover, the effect of DA dosage on the properties of MXene@PDA was explored. The structure and properties of MXene@PDA were tested and characterized using transmission electron microscopy, scanning electron microscopy, X-ray diffraction and ultraviolet-visible-near infrared spectroscopy. Results showed that PDA was successfully coated on the surfaces of MXene flakes, which improved the environmental stability of MXene. The best light absorption performance of the fabricated MXene@PDA was achieved when the mass ratio of MXene to DA was 100∶6. Under the irradiation of 100 mW/cm² xenon lamp, the temperature of MXene@PDA modified collagen aerogel was as high as 54.8 ℃, which was enhanced by 17.9 ℃ compared with pure collagen aerogel, and the maximum temperature was around 54.8 ℃ in several photothermal cycling experiments, showing the excellent photothermal conversion performance and cycling stability.

Key words: MXene, polydopamine, photothermal conversion, collagen, aerogel

中图分类号:

TS512

周建华, 晏亚飞, 周梦园. MXene@聚多巴胺的制备、性能和应用[J]. 皮革科学与工程, 2024, 34(1): 18-23.

ZHOU Jianhua, YAN Yafei, ZHOU Mengyuan. Preparation, Properties and Application of MXene@Polydopamine[J]. Leather Science and Engineering, 2024, 34(1): 18-23.

参考文献

[1] 陈珍,马建中,张文博,等.MXene的制备与改性及其在功能涂层中的应用[J].精细化工,2022,39(11):2173-2183.
CHEN Z,MA J Z,ZHANG W B,et al.Preparation and modification of MXene and its application in functional coatings[J].Fine Chemicals,2022,39(11):2173-2183.(in Chinese)
[2] 杨传玺,刘潇广,高畅,等.新型二维层状材料MXene在光催化水处理应用中的研究进展[J].工业水处理,2023,DOI:10.19965/j.cnki.iwt.2022-1053.
YANG C X,LIU X G,GAO C,et al.Research progress of MXene,a novel two-dimensional layered material,in photocatalytic water treatment[J].Industrial Water Treatment,2023,DOI:10.19965/j.cnki.iwt.2022-1053.(in Chinese)
[3] 陈文雪,靳丹丹,朱良亮,等.上转换@聚多巴胺纳米光热剂的制备及载药与抗菌性能[J].化学试剂,2023,45(1):54-61.
CHEN W X,JIN D D,ZHU L L,et al.Preparation and drug-carrying and antimicrobial properties of upconversion@poly(dopamine)nanophotothermolysis[J].Chemical Reagents,2023,45(1):54-61.(in Chinese)
[4] Du X S, Wang J A, Jin L Z, et al.Dopamine - decorated Ti₃C₂Tx MXene/cellulose nanofiber aerogels supported form-stable phase change composites with superior solar-thermal conversion efficiency and extremely high thermal storage density[J].ACS Applied Materials&Interfaces,2022,14:15225-15234.
[5] Chen Y X,Jiang Y,Feng W Q,et al.Construction of sensitive strain sensing nanofibrous membrane with polydopamine-modified MXene/CNT dual conductive network[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2022,635:128055-128082.
[6] Wan B L,Liu N N,Zhang Z,et al.Water-dispersible and stable polydopamine coated cellulose nanocrystal-MXene composites for high transparent,adhesive and conductive hydrogels[J]. Carbohydrate Polymers, 2023, 314: 120929-120940.
[7] Yun L,Zhao J,Kang X L,et al.Preparation and properties of monolithic and hydrophobic gelatin-silica composite aerogels for oil absorption[J].Journal of Sol-Gel Science and Technology,2017,83:197-206.
[8] 周建华,周梦园,李燕等.改性胶原气凝胶复合相变材料的制备及性能[J].精细化工,2022,39(6):1117-1124.
ZHOU J H,ZHOU M Y,LI Y,et al.Preparation and properties of modified collagen aerogel composite phase change materials[J]. Fine Chemical Industry, 2022, 39(6): 1117-1124. (in Chinese)
[9] 田振华,李幸,王浩.采用浸酸牛皮提取胶原及其性质表征[J].陕西科技大学学报,2019,37(10):17-23.
TIAN Z H,LI X,WANG H.Extraction of collagen using acid-impregnated cowhide and characterization of its properties[J].Journal of Shaanxi University of Science and Technology,2019,37(10):17-23.(in Chinese)
[10] Xiao L H,Jiong X W,Ying C,et al.A trace amount of MXene@PDA nanosheets for low-temperature zinc phosphating coatings with superb corrosion resistance[J].Applied Surface Science,2022,603:154455-154466.
[11] 薛妮. MXene的无氟法制备及性能研究[D].济南:山东大学,2022.
XUE N.Preparation and properties of MXene by fluorine - free method[D].Jinan:Shandong University,2022.(in Chinese)
[12] Yong L,Yu H X,Wei G,et al.Boosting fire safety and mechanical performance of thermoplastic polyurethane by the face-to-face two-dimensional phosphorene/MXene architecture[J].Journal of Materials Science&Technology,2022,129(34):27-39.
[13] Berdiyorov G R.Optical properties of functionalized Ti₃C₂T₂(T=F,O,OH)MXene:First-principles calculations[J].AIP Advances,2016,6(5):55105-55113.
[14] 郭晚秋. 二维层状Ti₃C₂Tx的制备、光学性质研究及其在潜指纹检测中的应用[D].长春:东北师范大学,2020.
GUO L Q.Preparation and optical characterization of two- dimensional layered Ti₃C₂Tx and its application in latent fingerprint detection[D].Changchun:Northeast Normal University,2020.(in Chinese)
[15] Simon J D.Spectroscopic and dynamic studies of the epidermal chromophores trans-urocanic acid and eumelanin[J].Accounts of Chemical Research,2000,33(5):307-313.
[16] 颜绮雯. 含香豆素类化合物的刺激响应薄膜的制备及其性能研究[D].上海:华东师范大学,2021.
Yen Y W.Preparation of stimuli-responsive films containing coumarin analogs and study of their properties[D].Shanghai:East China Normal University,2021.(in Chinese)
[17] Lee G S,Yun T,Kim H,et al.Mussel inspired highly aligned Ti₃C₂Tx MXene film with synergistic enhancement of mechanical strength and ambient stability[J].ACS Nano,2020,14(9):11722-11732.
[18] Riesz J,Sarna T,Meredith P.Radiative relaxation in synthetic pheomelanin[J].Journal of Physical Chemistry B,2006,110(28):13985-13990.
[19] Xu D X,Li Z D,Li L S,et al.Insights into the Photothermal Conversion of 2D MXene nanomaterials:Synthesis,mechanism,and applications[J].Advanced Functional Materials,2020,30(47):712-733.
[20] Zhao W W,Wang H,Han Y,et al.Dopamine/phosphorylcholine copolymer as an efficient joint lubricant and ROS scavenger for the treatment of osteoarthritis[J].ACS Applied Materials and Interfaces,2020,12(46):51236-51248.
[21] Liu Y L,Ai K L,Lu L H.Polydopamine and its derivative materials:synthesis and promising applications in energy,Environmental,and Biomedical Fields[J].Chemical Reviews,2014,114(9):5057-5115.
[22] Cho J H,Shanmuganathan K,Ellison C J.Bioinspired catecholic copolymers for antifouling surface coatings[J].ACS Applied Materials&Interfaces,2013,5(9):3794-3802.
[23] Guo Z,Sun C,Wang J,et al.High-performance laminated fabric with enhanced photothermal conversion and joule heating effect for personal thermal management[J].ACS Applied Materials&Interfaces,2021,13(7):8851-8862.

MXene@聚多巴胺的制备、性能和应用

Preparation, Properties and Application of MXene@Polydopamine

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	王再学, 康明慧, 张兆红, 龙忠珍, 徐云慧, 冯莉. 胶原蛋白肽/硅橡胶复合材料亲水性研究[J]. 皮革科学与工程, 2024, 34(1): 83-87.
[2]	张琦弦, 孙青永, 石碧. 羧基化胶原纤维的制备及其对黄酮苷类化合物的分离特性[J]. 皮革科学与工程, 2023, 33(6): 8-16.
[3]	乐薇, 张旭, 秦子波, 余小月, 熊善柏, 胡杨. 不同结构的多酚交联对胶原水凝胶理化性质的影响[J]. 皮革科学与工程, 2023, 33(5): 1-7.
[4]	白忠薛, 王学川, 李彤, 李佳俊, 冯宇宇, 黄梦晨, 岳欧阳, 刘新华. 胶原化学改性及应用进展[J]. 皮革科学与工程, 2023, 33(5): 40-47.
[5]	李盛龙, 曹珊, 王新德, 姬明宇. 胶原/胶原肽螯合生物可及性金属的研究进展[J]. 皮革科学与工程, 2023, 33(5): 48-54.
[6]	熊永铭, 李国英. 乙醇/苹果酸强化碳化二亚胺改性胶原膜的研究[J]. 皮革科学与工程, 2023, 33(3): 1-6.
[7]	曾奕苇, 刘海, 沙川路, 周加境, 李蕙. 3D打印胶原基材料及其在口腔组织再生修复中的应用[J]. 皮革科学与工程, 2023, 33(2): 47-54.
[8]	秦子波, 余小月, 乐薇, 荣建华, 熊善柏, 胡杨. 牛跟腱胶原与草鱼皮胶原的结构表征及自组装行为比较[J]. 皮革科学与工程, 2023, 33(1): 1-8.
[9]	张军涛, 汪海波, 徐丽明. 水产胶原的热稳定性能和生物医学应用研究进展[J]. 皮革科学与工程, 2023, 33(1): 46-53.
[10]	张军涛, 汪海波, 徐丽明. 水产胶原的制备工艺及自组装性能研究进展[J]. 皮革科学与工程, 2022, 32(6): 32-38.
[11]	白龙, 金勇, 商翔, 林芯颖, 周荣. 胶原基离子水凝胶的制备及其在传感领域的应用研究[J]. 皮革科学与工程, 2022, 32(5): 1-5.
[12]	黄婷, 马贺伟, 王泽胜, 范慧琳, 陈勇, 许洁. 胶原纤维负载MnO₂的制备及其对甲醛的催化去除[J]. 皮革科学与工程, 2022, 32(5): 14-18.
[13]	程玉林, 李国英. 衣康酸酐改性胶原制备光固化水凝胶[J]. 皮革科学与工程, 2022, 32(4): 14-19.
[14]	丁绍兰, 刘云, 李重遥. 耐铬厌氧胶原蛋白水解菌的筛选及应用研究[J]. 皮革科学与工程, 2022, 32(3): 30-35.
[15]	冯荣欣, 杨娜, 但年华, 王康建, 陈一宁, 但卫华. 四川路黄牛蓝湿革和黄牛鞋面革的组织学特征[J]. 皮革科学与工程, 2022, 32(2): 21-25.