乙醇/苹果酸强化碳化二亚胺改性胶原膜的研究

doi:10.19677/j.issn.1004-7964.2023.03.001

皮革科学与工程 ›› 2023, Vol. 33 ›› Issue (3): 1-6.doi: 10.19677/j.issn.1004-7964.2023.03.001

• 试验研究 • 下一篇

乙醇/苹果酸强化碳化二亚胺改性胶原膜的研究

熊永铭^1,2, 李国英^1,2,*

1.四川大学皮革化学与工程教育部重点实验室,四川成都 610065;
2.四川大学制革清洁技术国家工程实验室,四川成都 610065

收稿日期:2022-12-13 出版日期:2023-06-01 上线日期:2023-05-17
通讯作者: *李国英（1967-）,女,教授,博士生导师,研究方向为胶原化学及其生物学利用。E-mail：liguoyings@163.com。
作者简介:熊永铭（1998-）,男,硕士研究生,研究方向为皮革化学与工程。E-mail：1584696474@qq.com。
基金资助:
国家自然科学基金资助项目（22078206）

Study on the Carbodiimide Hydrochloride -Modified Collagen Film Improved by Ethanol/Malic Acid

XIONG Yongming^1,2, LI Guoying^1,2,*

1. Key Laboratory of Leather Chemistry and Engineering of Ministry of Education, Sichuan University, Chengdu 610065, China;
2. National Engineering Laboratory for Clean Technology of Leather Manufacture, Sichuan University, Chengdu 610065, China

Received:2022-12-13 Online:2023-06-01 Published:2023-05-17

摘要/Abstract

摘要： 作为一种可食用的绿色环保材料,胶原膜被广泛应用于食品包装,但较弱的机械性能限制了其进一步应用。论文探究了碳酰二亚胺在水相（A_W-COL）、乙醇/水双相（A_W/E-COL）和含苹果酸的乙醇/水双相中（A_W/E-MA）对胶原膜的改性效果。结果表明,A_W/E-COL和A_W/E-MA改性后的胶原膜中形成较多酰胺键,膜的耐水性、耐酶解性、热稳定性、蒸煮性和力学性能明显提高。其中,A_W/E-MA改性后,胶原膜干强度和湿强度分别从（92.90±5.21）MPa和（3.21±0.32）MPa提高到（163.36±10.55）MPa和（24.64±4.19）MPa。然而,A_W-COL改性对胶原膜性能提升不明显,这可能是膜中酰胺键生成较少且结构受到一定破坏所致。研究表明,A_W/E-MA改性后的胶原膜理化性质优异,是一种具有较大应用价值的食品包装材料。

关键词: 胶原膜, 苹果酸, 乙醇, 碳酰二亚胺, 力学性能

Abstract: As an edible and green material, collagen film has been widely used in food packaging, but the weak mechanical properties limit its further application. This work investigated the modification of collagen films by carbodiimide hydrochloride in aqueous (A_W-COL), ethanol/water biphasic (A_W/E-COL) and the malic acid-containing ethanol/water biphasic (A_W/E-MA) solutions, respectively. The results showed that more cross-linking bonds had been formed in the collagen films by the modification in A_W/E-COL and A_W/E-MA, leading to the improvement in their water resistance, enzymatic hydrolysis resistance, thermal stability, cooking performance and mechanical property. After the modification in A_W/E-MA, the dry strength and wet strength of collagen film increased from (92.90 ± 5.21) MPa and (3.21 ± 0.32) MPa to (163.36 ± 10.55) MPa and (24.64 ± 4.19) MPa, respectively. However, the modification in A_W-COL did not significantly improve the performance of collagen film, which may be caused by the less formation of cross-linking bonds in the film and some damage to its structure. The present collagen film modified in A_W/E-MA had excellent physical and chemical properties, and is expected to have great potential application value as a food packing material.

Key words: collagen film, malic acid, ethanol, carbodiimide hydrochloride, mechanical property

中图分类号:

TS512

熊永铭, 李国英. 乙醇/苹果酸强化碳化二亚胺改性胶原膜的研究[J]. 皮革科学与工程, 2023, 33(3): 1-6.

XIONG Yongming, LI Guoying. Study on the Carbodiimide Hydrochloride -Modified Collagen Film Improved by Ethanol/Malic Acid[J]. Leather Science and Engineering, 2023, 33(3): 1-6.

参考文献

[1] Muncke J.Tackling the toxics in plastics packaging[J].PLoS Biology,2021,19(3):e3000961.
[2] Wang H,Qian J,Ding F.Emerging chitosan-based films for food packaging applications[J].Journal of Agricultural and Food Chemistry,2018,66(2):395-413.
[3] Mohamed S A A,El-Sakhawy M,Nashy E H A,et al.Novel natural composite films as packaging materials with enhanced properties[J].International Journal of Biological Macromolecules,2019,136:774-84.
[4] Wang W,Liu Y,Liu A,et al.Effect ofin situapatite on performance of collagen fiber film for food packaging applications[J].Journal of Applied Polymer Science,2016,133(44):44154.
[5] 秦子波,余小月,乐薇,等.牛跟腱胶原与草鱼皮胶原的结构表征及自组装行为比较[J].皮革科学与工程,2023,33(1):1-8.
[6] 胡可欣,李国英.漆酶催化没食子酸改性胶原蛋白膜的研究[J].皮革科学与工程,2021,21(3):7-13.
[7] Bose S,Li S,Mele E,et al.Dry vs.wet:Properties and performance of collagen films.Part I.Mechanical behaviour and strain-rate effect[J].Journal of Mechanical Behavior Biomedical Materials,2020,111:103983.
[8] Wang W,Zhang Y,Ye R,et al.Physical crosslinkings of edible collagen casing[J].International Journal of Biological Macromolecules,2015,81:920-925.
[9] Chen X,Zhou L,Xu H,et al.The structure and properties of natural sheep casing and artificial films prepared from natural collagen with various crosslinking treatments[J].International Journal of Biological Macromolecules,2019,135:959-968.
[10] Xu J,Liu F,Yu Z,et al.Influence of softwood cellulose fiber and chitosan on the film-forming properties of collagen fiber[J].Food Bioscience,2021,42:101056.
[11] Wang K,Wang W,Ye R,et al.Mechanical properties and solubility in water of corn starch-collagen composite films:Effect of starch type and concentrations[J].Food Chemistry,2017,216:209-216.
[12] Chen C,Liu F,Yu Z,et al.Improvement in physicochemical properties of collagen casings by glutaraldehyde cross-linking and drying temperature regulating[J].Food Chemistry,2020,318:126404.
[13] Safandowska M,Pietrucha K.Effect of fish collagen modification on its thermal and rheological properties[J].International Journal of Biological Macromolecules,2013,53:32-37.
[14] Nam K,Kimura T,Funamoto S,et al.Preparation of a collagen/polymer hybrid gel designed for tissue membranes.Part I:Controlling the polymer-collagen cross-linking process using an ethanol/water co-solvent[J].Acta Biomaterialia,2010,6(2):403-408.
[15] 刘文涛,白聪,沈里瑞.黑鱼胶原溶液的流变、热稳定性及化学交联改性研究[J].皮革科学与工程,2022,32(1):1-8.
[16] Yang H,Li Q,Liu S,et al.Acetic acid/1-ethyl-3-methy limidazolium acetate as a biphasic solvent system for altering the aggregation behavior of collagen molecules[J].Journal of Molecular Liquids,2018,262:78-85.
[17] Lee S,Zhang M,Wang G,et al.Characterization of polyvinyl alcohol/starch composite films incorporated with p-coumaric acid modified chitosan and chitosan nanoparticles:A comparative study[J].Carbohydrate Polymers,2021,262:117930.
[18] Ji F,Zhou W,Zhang Z,et al.Effects of relative molecular weight distribution and isoelectric point on the swelling behavior of gelatin films[J]. Frontiers in Chemistry, 2022, 10:857976.
[19] Wu J,Liu F,Yu Z,et al.Facile preparation of collagen fiber-glycerol-carboxymethyl cellulose composite film by immersing method[J].Carbohydrate Polymers,2020,229:115429.
[20] Yan M,An X,Duan S,et al.A comparative study on cross-linking of fibrillar gel prepared by tilapia collagen and hyaluronic acid with EDC/NHS and genipin[J].International Journal of Biological Macromolecules,2022,213:639-650.
[21] Xiao J,Ma Y,Wang W,et al.Incorporation of gelatin improves toughness of collagen films with a homo-hierarchical structure[J].Food Chemistry,2021,345:128802.
[22] Liu K,Zhu B,Duan T,et al.Transparency of chrysotile nanofiber-reinforced nanocomposite films:Effect of Rayleigh scattering[J].Composites Science and Technology,2015,119:68-74.
[23] Shi D,Liu F,Yu Z,et al.Effect of aging treatment on the physicochemical properties of collagen films[J].Food Hydrocolloids,2019,87:436-447.
[24] Wang W,Zhang X,Li C,et al.Using carboxylated cellulose nanofibers to enhance mechanical and barrier properties of collagen fiber film by electrostatic interaction[J].Journal of Science Food and Agriculture,2018,98(8):3089-3097.
[25] Shimizu M,Saito T,Isogai A.Water-resistant and high oxygen-barrier nanocellulose films with interfibrillar cross- linkages formed through multivalent metal ions[J].Journal of Membrane Science,2016,500:1-7.
[26] 黄婷,马和伟,王泽生,等.胶原纤维负载MnO₂的制备及其对甲醛的催化去除[J].皮革科学与工程,2022,32(5):14-18.
[27] Duan L,Yuan Q,Xiang H,et al.Fabrication and characterization of a novel collagen-catechol hydrogel[J].Journal of Biomaterials Applications,2018,32(7):862-870.
[28] Nishad Fathima N.Effect of zirconium(IV)complexes on the thermal and enzymatic stability of type I collagen[J].Journal of Inorganic Biochemistry,2003,95(1):47-54.
[29] Ma Y X,Ma Y,Yu Z,et al.Calcium spraying for fabricating collagen-alginate composite films with excellent wet mechanical properties[J].Food Hydrocolloids,2022,124:107340.

乙醇/苹果酸强化碳化二亚胺改性胶原膜的研究

Study on the Carbodiimide Hydrochloride -Modified Collagen Film Improved by Ethanol/Malic Acid

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