胶原蛋白肽/硅橡胶复合材料亲水性研究

doi:10.19677/j.issn.1004-7964.2024.01.012

皮革科学与工程 ›› 2024, Vol. 34 ›› Issue (1): 83-87.doi: 10.19677/j.issn.1004-7964.2024.01.012

胶原蛋白肽/硅橡胶复合材料亲水性研究

王再学^1,2, 康明慧², 张兆红², 龙忠珍^1,3, 徐云慧², 冯莉^1,*

1.中国矿业大学化工学院,江苏徐州 221116;
2.徐州工业职业技术学院材料工程学院,江苏徐州 221140;
3.徐州鸿丰高分子材料有限公司,江苏徐州 221200

收稿日期:2023-03-28 修回日期:2023-10-13 接受日期:2023-11-05 出版日期:2024-02-01 上线日期:2024-01-08
通讯作者: *冯莉（1966-）,女,教授,博士生导师,研究方向：功能高分子材料研究。E-mail:cumthgfl@163.com。
作者简介:王再学（1981-）,男,副教授,博士生,研究方向：高分子材料改性研究。E-mail:wangzx@mail.xzcit.cn。
基金资助:
2021年江苏高校“青蓝工程”项目; 江苏省产学研合作项目（BY2021345）; 江苏省高职院校教师专业带头人高端研修项目（2020GRGDYX098）; 徐州市科技项目（KC21042）

Study on the Hydrophilicity of Collagen Peptide/MVQ Composites

WANG Zaixue^1,2, KANG Minghui², ZHANG Zhaohong², LONG Zhongzhen^1,3, XU Yunhui², FENG Li^1,*

1. China University of Mining and Technology, College of Chemical Engineering, Xuzhou 221116, China;
2. Xuzhou College of Industrial Technology, Department of Material Engineering, Xuzhou 221140, China;
3. Xuzhou Hoffen Chemicals Co., LTD, Xuzhou 221200, China

Received:2023-03-28 Revised:2023-10-13 Accepted:2023-11-05 Online:2024-02-01 Published:2024-01-08

摘要/Abstract

摘要： 利用双辊开炼机将胶原蛋白肽加入硅橡胶中,制备胶原蛋白肽/硅橡胶复合材料。结果表明：胶原蛋白肽在复合材料中有结构控制剂和延迟硫化的作用;随着胶原蛋白肽用量的增加,复合材料的硬度增加,100%定伸应力从1.92 MPa增至2.66 MPa;拉伸强度和撕裂强度降低。当复合材料中胶原蛋白肽含量为4份时,复合材料的最大热失重速率温度比纯硅橡胶降低1.6%,说明加入胶原蛋白肽,降低了复合材料热稳定性;复合材料红外光谱中出现了硅橡胶和胶原蛋白肽的特征峰;接触角比纯硅橡胶降低了4.5%,说明复合材料的亲水性有一定改善。

关键词: 胶原蛋白肽, 硅橡胶, 亲水性

Abstract: Collagen peptide/Methyl vinyl silicone rubber（MVQ） composites were prepared by adding biomaterial collagen peptide to MVQ using double-roller mill. The results showed that collagen peptide had the effects of structure control agent and delayed vulcanization. With the increasing of the amount of collagen peptide,the composite's hardness increased, and the 100% tensile stress was improved from 1.92 MPa to 2.66 MPa, but its tensile strength and tear strength decreased. When the collagen peptide content was 4 per hundred of rubber, the maximum thermal weight loss rate temperature of the composite was 1.6% lower than that of MVQ. The characteristic peaks of MVQ and collagen peptide appeared in the infrared spectrum of the composites, and the hydrophilicity had been improved to a certain extent. The contact angle decreased by 4.5% at 4 per hundred of rubber.

Key words: collagen peptide, Methyl vinyl silicone rubber, hydrophilicity

中图分类号:

TS512

王再学, 康明慧, 张兆红, 龙忠珍, 徐云慧, 冯莉. 胶原蛋白肽/硅橡胶复合材料亲水性研究[J]. 皮革科学与工程, 2024, 34(1): 83-87.

WANG Zaixue, KANG Minghui, ZHANG Zhaohong, LONG Zhongzhen, XU Yunhui, FENG Li. Study on the Hydrophilicity of Collagen Peptide/MVQ Composites[J]. Leather Science and Engineering, 2024, 34(1): 83-87.

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胶原蛋白肽/硅橡胶复合材料亲水性研究

Study on the Hydrophilicity of Collagen Peptide/MVQ Composites

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