皮革科学与工程 ›› 2022, Vol. 32 ›› Issue (5): 1-5.doi: 10.19677/j.issn.1004-7964.2022.05.001

• 试验研究 •    下一篇

胶原基离子水凝胶的制备及其在传感领域的应用研究

白龙1,2, 金勇1,2,*, 商翔1,2, 林芯颖1,2, 周荣1,2   

  1. 1.四川大学皮革化学与工程教育部重点实验室,四川 成都 610065;
    2.四川大学制革清洁技术国家工程实验室,四川 成都 610065
  • 收稿日期:2022-03-15 出版日期:2022-10-28 上线日期:2022-10-10
  • 通讯作者: *金勇(1968-),男,教授,主要从事高分子类皮革化工材料的合成及应用研究,E-mail:jinyong@scu.edu.cn。
  • 作者简介:白龙(1993-),男,博士研究生,E-mail:rhylongbai@163.com。
  • 基金资助:
    国家自然科学基金(No.22078207); 四川省科学技术项目(2021ZHCG0042); 中央高校基本科研业务费

Preparation of Collagen-based Ionic Hydrogel and its Application in Sensing Field

BAI Long1,2, JIN Yong1,2,*, SHANG Xiang1,2, LIN Xinying1,2, ZHOU Rong1,2   

  1. 1. Key Laboratory of Leather Chemistry and Engineering of Ministry of Education, Sichuan University, Chengdu 610065, China;
    2. National Engineering Laboratory for Clean Technology of Leather Manufacture, Sichuan University, Chengdu 610065, China
  • Received:2022-03-15 Online:2022-10-28 Published:2022-10-10

摘要: 针对目前胶原基水凝胶传感材料力学性能不足和电传感不灵敏问题,以胶原、AlCl3·6H2O和丙烯酸为原料,开发了一种兼具超强拉伸性及快速电信号响应能力的胶原基离子水凝胶,并研究了该水凝胶的机械力学、导电和传感性能及其在人体运动监测领域的实际应用。结果表明,由于引入胶原和Al3+离子,水凝胶被赋予了超强的拉伸性能(>2000%)和优异的导电能力(0.4 S/m)。同时,该水凝胶可以在203 ms内快速监测5%~300%范围内的拉伸变形。将该水凝胶贴在人体皮肤表面,可精确地监测各种人体运动(如手指弯曲、胳膊运动及人体呼吸等),在智能穿戴及医疗诊断领域显示出了广阔的应用前景。

关键词: 胶原, 离子水凝胶, 超强拉伸性, 电信号传感, 人体运动监测

Abstract: To address the problems of insufficient mechanical properties and insensitive electrical sensing of current collagen-based hydrogel sensing materials, this paper develops a new collagen-based ionic hydrogel with super stretchability and fast electrical signal response capability using collagen, AlCl3·6H2O and acrylic acid, and investigates the mechanical properties, conductivity and sensing properties of the hydrogel and its practical applications in the field of smart wear. The results show that owing to the introduction of collagen and Al3+ ions, the hydrogel can be endowed with high stretchability (>2000%) and excellent electrical conductivity (0.4 S/m). Meanwhile, the hydrogel can rapidly monitor 5%~300% tensile deformation within 203 ms. By mounting the hydrogel on the human skin, various human movements (such as finger flexion, arm movement, and human breathing) can be accurately monitored, showing broad application prospects in smart wear and medical diagnostics.

Key words: collagen, ionic hydrogel, highly stretchability, electrical sensing, human motion detection

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