超细纤维合成革透水汽性能的研究进展

doi:10.19677/j.issn.1004-7964.2024.01.009

皮革科学与工程 ›› 2024, Vol. 34 ›› Issue (1): 61-68.doi: 10.19677/j.issn.1004-7964.2024.01.009

超细纤维合成革透水汽性能的研究进展

闫子妍¹, 赵立环^1,*, 王玉稳², 杨玉洁¹, 李艳艳¹, 陈雨龙¹

1.天津工业大学纺织科学与工程学院,天津 300387;
2.天津齐邦新材料有限公司,天津 300380

收稿日期:2023-05-23 修回日期:2023-07-20 接受日期:2023-07-25 出版日期:2024-02-01 上线日期:2024-01-08
通讯作者: *赵立环（1981-）,女,博士,副教授,硕士生导师,研究方向：新型非织造材料的制备、理论及应用。E-mail: zhaolihuan@tiangong.edu.cn。
作者简介:闫子妍（2000-）,女,硕士研究生,研究方向为超细纤维合成革基布。E-mail: yanzy9529@163.com。
基金资助:
天津市科技计划项目（22YDTPJC00820）; 中国纺织工业联合会科技指导性计划项目(2021065)

Research Progress of Water Vapor Permeability of Microfiber Synthetic Leather

YAN Ziyan¹, ZHAO Lihuan^1,*, WANG Yuwen², YANG Yujie¹, LI Yanyan¹, CHEN Yulong¹

1. School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China;
2. Chybond Materials Co., Ltd., Tianjin 300380, China

Received:2023-05-23 Revised:2023-07-20 Accepted:2023-07-25 Online:2024-02-01 Published:2024-01-08

摘要/Abstract

摘要： 超细纤维合成革（简称超纤革）是替代天然皮革的理想材料,但超纤革的透水汽性能与天然皮革相比仍存在差距,有待提升。文章概述了超纤革的制备过程,分析了超纤革的性能及其在透水汽性能方面的不足,并从超纤革的主要组分,即超纤革基布和聚氨酯树脂入手,探讨了超纤革透水汽性能研究的最新进展;总结了对超纤革基布的水解、增加活性基团和亲水剂等改性方法,阐述了对聚氨酯树脂的填料、接枝聚合和共混等改性措施,探讨了对超纤革的后整理改性选项,最后提出了超纤革透水汽性能研究的未来发展方向。

关键词: 超细纤维合成革, 透水汽性能, 革基布, 聚氨酯树脂, 改性

Abstract: Microfiber synthetic leather is an ideal material to replace natural leather, but its water vapor permeability performance is still far from that of natural leather. The process of preparing microfiber leather was discussed in this paper, and the properties of microfiber leather and its deficiencies in water vapor permeability were analyzed. Specifically, the progress of research on the water vapor permeability of microfiber leather was discussed from the two main components of microfiber leather, namely microfiber leather base fabric and polyurethane resin. The modification of microfiber leather base fabric by hydrolysis, the addition of reactive groups and hydrophilic agents was summarized. The modification of polyurethane resin by filler, graft polymerization and co-blending was also discussed. Moreover, the modification of microfiber leather by finishing was discussed. Finally, the research direction for the water vapor permeability of microfiber leather was proposed.

Key words: microfiber synthetic leather, water vapor permeability, leather base fabric, polyurethane resin, modification

中图分类号:

TS565

闫子妍, 赵立环, 王玉稳, 杨玉洁, 李艳艳, 陈雨龙. 超细纤维合成革透水汽性能的研究进展[J]. 皮革科学与工程, 2024, 34(1): 61-68.

YAN Ziyan, ZHAO Lihuan, WANG Yuwen, YANG Yujie, LI Yanyan, CHEN Yulong. Research Progress of Water Vapor Permeability of Microfiber Synthetic Leather[J]. Leather Science and Engineering, 2024, 34(1): 61-68.

参考文献

[1] BAI Z,WANG X,ZHENG M,et al.Leather for flexible multifunctional bio-based materials:a review[J].Journal of Leather Science and Engineering,2022,4(1):16.
[2] MUTHUKRISHNAN L.Nanotechnol-ogy for cleaner leather production:a review[J].Environmental Chemistry Letters,2021,19(3):2527-2549.
[3] 朵永超,钱晓明,赵宝宝,等.超细纤维合成革基布的制备及其性能[J].纺织学报,2020,41(9):81-87.
DUO Y C,QIAN X M,ZHAO B B,et al.Preparation of microfiber synthetic leather base fabric and its properties[J].Journal of Textiles,2020,41(9):81-87.(in Chinese)
[4] 朵永超,钱晓明,赵宝宝,等.超纤革仿天然皮革研究进展[J].中国皮革,2019,48(3):41-45+53.
DUO Y C,QIAN X M,ZHAO B B,et al.Research progress of microfiber leather imitating natural leather[J].China Leather,2019,48(3):41-45+53.(in Chinese)
[5] CHEN M, ZHOU D L, CHEN Y, et al.Analyses of structures for a synthetic leather made of polyurethane and microfiber[J].Journal of Applied Polymer Science,2007,103(2):903-908.
[6] ZHAO B,QIAN Y,QIAN X,et al.Preparation and properties of split microfiber synthetic leather[J].Journal of Engineered Fibers and Fabrics,2018,13(2):15-21.
[7] 陈宇,易杰,庞明,等.基于水性聚氨酯超纤革开纤工艺研究进展[J].西部皮革,2020,42(3):36-37.
CHEN Y,YI J,PANG M,et al.Research progress of open fiber process based on water-based polyurethane microfiber leather[J].Western Leather,2020,42(3):36-37.(in Chinese)
[8] BASAK S,SHAKYAWAR D,SAMANTA K K,et al.Development of natural fibre based flexural composite:A sustainable mimic of natural leather[J].Materials Today Communications,2022,32:103976.
[9] SUN Z,WEN J,GUAN J,et al.Preparation,mechanical and thermal properties of polydimethylsiloxane coating for synthetic leathers[J].Journal of Coatings Technology and Research,2022:1-13.
[10] WANG Y,JIN L.Preparation and characterization of self-colored waterborne polyurethane and its application in eco-friendly manufacturing of microfiber synthetic leather base[J].Polymers,2018,10(3):289.
[11] 赵宝宝,钱幺,钱晓明,等.水性聚氨酯膜的制备及在超纤革中的应用[J].高分子材料科学与工程,2017,33(10):135-140.
ZHAO B B,QIAN Y,QIAN X M,et al.Preparation of water-based polyu-rethane film and its application in microfiber leather[J].Polymer Mater-ials Science and Engineering,2017,33(10):135-140.(in Chinese)
[12] 高磊,牛家嵘,金欣,等.超细纤维合成革柔软改性的研究进展[J].皮革科学与工程,2022,32(4):54-59.
GAO L,NIU J R,JIN X,et al.Research progress on soft modification of microfiber synthetic leather[J].Leather Sci and Eng,2022,32(4):54-59.(in Chinese)
[13] 王杨阳,强涛涛,王乐智,等.改善超细纤维合成革卫生性能的工艺设计与优化[J].上海纺织科技,2017,45(6):32-36+39.
WANG Y Y,QIANG T T,WANG L Z,et al.Process design and optimizat-ion for improving the hygienic prop-erties of microfiber synthetic leather[J].Shanghai Textile Science and Tec-hnology,2017,45(6):32-36+39.(in Chinese)
[14] 强涛涛,王杨阳,王学川,等.改善超细纤维合成革卫生性能的研究进展[J].纺织导报,2015,859(6):89-92.
QIANG T T,WNAG Y Y,WANG X C,et al.Research progress on improving the hygienic properties of microfiber synthetic leather[J].Textile Guide,2015,859(6):89-92.(in Chinese)
[15] 王学川,王沛懿,强涛涛,等.改善超细纤维合成革透水汽性能的研究进展[J].中国皮革,2012,41(17):7-11.
WANG X C,WANG P Y,QIANG T T,et al.Research progress on improving the water vapor permeability of microfiber synthetic leather[J].China Leather,2012,41(17):7-11.(in Chinese)
[16] DUO Y,QIAN X,ZHAO B,et al.Improving hygiene performance of microfiber synthetic leather base by mixing polyhydroxybutyrate nanofiber[J].Journal of Engineered Fibers and Fabrics,2019.
[17] BIGANSKA O,DARQUE‐CERETTI E,GIULIERI F,et al.Characterization of finishing on polyamide fibres[J].Surface and Interface Analysis:An International Journal devoted to the development and application of techniques for the analysis of surfaces,interfaces and thin films,2001,31(9):847-855.
[18] 王晓芹. 胶原蛋白改性超细纤维合成革基布及其机理研究[D].西安:陕西科技大学,2015.
WANG X Q.Collagen modified microfiber synthetic leather base fabric and its mechanism[D].Xi'an:Shaanxi University of Science and Technology,2015.(in Chinese)
[19] 马兴元,王俊君,易宗俊,等.提高超细纤维合成革透水汽性能的研究[J].皮革科学与工程,2007,85(3):43-46+49.
MA X Y,WANG J J,YI Z J,et al.Study on improving the water vapor per-meability of microfiber synthetic leather[J].Leather Sci and Eng,2007,85(3):43-46+49.(in Chinese)
[20] KISNER A,RAINERT K T,FERRARI F,et al.Chemical functionalization of polyamide 6.6 fabrics[J].Reactive& Functional Polymers,2013,73(10):1349-1356.
[21] 马兴元,吕凌云,李哓.聚酰胺超细纤维合成革基布的酶法改性研究[J].中国皮革,2010,39(5):36-39+46.
MA X Y,LV L Y,LI X.Study on enzymatic modification of polyamide microfiber synthetic leather base fabric[J].China Leather,2010,39(5):36-39+46.(in Chinese)
[22] KANELLI M,VASILAKOS S,LADAS S,et al.Surface modification of polyamide 6.6 fibers by enzymatic hydrolysis[J].Process Biochemistry,2017,59:97-103.
[23] QIANG T,WANG X,WANG X,et al.Study on the improvement of water vapor permeability and moisture absorption of microfiber synthetic leather base by collagen[J].Textile Research Journal,2015,85(13):1394-1403.
[24] WANG X,XU N,GUO P,et al.Improving moisture absorbent and transfer abilities by modifying superfine fiber synthetic leather base with collagen-chrome tannins[J].Textile Research Journal,2016,86(7):765-775.
[25] WANG X,WANG X,QIANG T,et al.Modification of microfiber synthetic leather base and model by collagen[J].Journal of Engineered Fibers and Fabrics,2015,10(2).
[26] XU N,XING Y,WANG X,et al.Construction of waste‐collagen modified superfine fiber substrates based on“click”chemistry:Moisture absorption and permeability[J].Journal of Applied Polymer Science,2022,139(1):51440.
[27] REN L,WANG N,SUN S,et al.Improvement of the sanitary property of microfiber synthetic leather base by PAMAM[J].Journal of Engineered Fibers and Fabrics,2015,10(2).
[28] LI L,LIU S,LIU R,et al.Preparation and characterization of hydrophilic wetting-modified polyamide fibers[J].Advances in Polymer Technology,2020,2020:1-7.
[29] SUN Y F,ZHOU X D.Preparation and application of a novel durable hydrophilic finishing agent for polyamide fabric[J].Journal of the Textile Institute,2019,110(9):1300-1306.
[30] KUANG X H,GUAN J P,TANG R C,et al.Surface functionalization of polyamide fiber via dopamine polymerization[J].Materials Research Express,2017,4(9).
[31] HONARKAR H.Waterborne polyurethanes:A review[J].Journal of Dispersion Science and Technology,2018,39(4):507-516.
[32] 冯见艳,王学川,张哲,等.聚氨酯合成革绿色清洁化生产发展趋势分析与探讨[J].皮革科学与工程,2018,28(1):25-29+45.
FENG J Y,WANG X C,ZHANG Z,et al.Analysis and discussion on the development trend of green and clean production of polyurethane synthetic leather[J].Leather Sci and Eng,2018,28(1):25-29+45.(in Chinese)
[33] CAI W,XIN W,ZHANG H,et al.Synthesis and application of a low dye absorption waterborne polyurethane for microfiber synthetic leather[J].Coatings,2022,12(6):728.
[34] LIU X,HONG W,CHEN X.Continuous production of water-borne polyurethanes:A review[J].Polymers,2020,12(12):2875.
[35] YOUSEFI E,DOLATI A,NAJAFKHANI H.Preparation of robust antistatic waterborne polyurethane coating[J].Progress in Organic Coatings,2020,139:105450.
[36] MARTINS G S,PEREIRA I M,HOEHNE N M,et al.Influence of aqueous dispersions in place of organic solvents during the synthesis of shape memory polyurethanes on their structure and properties[J].Polymer Engineering&Science,2017,57(4):432-440.
[37] 杨献金,张子明,李勇.水性聚氨酯在合成革干法涂层中的应用研究[J].皮革科学与工程,2023,33(2):55-61+80.
YANG X J,ZHANG Z M,LI Y,et al.Research on the application of water-based polyurethane in dry coating of synthetic leather[J].Leather Sci and Eng,2023,33(02):55-61+80.(in Chinese)
[38] 水性PU树脂的性能优势[J].材料保护,2022,55(9):113.
Performance advantages of waterborne PU resin[J].Material Protection,2022,55(9):113.(in Chinese)
[39] 吕泽瑜,孙慧,吕竹明,等.合成革工业的绿色制造路径探索[J].皮革科学与工程,2022,32(5):35-39.
LV Z Y,SUN H,LV Z M,et al.Exploration of green manufacturing path in synthetic leather industry[J].Leather Sci and Eng,2022,32(5):35-39.(in Chinese)
[40] XU T,XU H,ZHONG Y,et al.Preparation and characteristics of sepiolite-waterborne polyurethane composites[J].Journal of Polymer Engineering,2022,42(1):66-74.
[41] MA J,WANG T.Preparation and characterization of water‐absorbing polyurethane foam composites with microsized sodium polyacrylate particles[J].Journal of Applied Polymer Science,2018,135(39):46702.
[42] MU C,CHEN H,SUN X,et al.MoS₂@ZIF-8 doped waterborne polyurethane membranes with water vapor permeable,lubricating,and antibacterial properties[J].Progress in Organic Coatings,2021,161:106465.
[43] HAN Y,JIANG Y,HU J.Collagen incorporation into waterborne polyurethane improves breathability,mechanical property,and self-healing ability[J].Composites Part A:Applied Science and Manufacturing,2020,133:105854.
[44] WU G,SONG X,YANG Z,et al.Biodegradability of renewable waterborne polyurethane modified with vinyl-grafted gelatin by UV curing[J].Polymer Bulletin,2022:1-24.
[45] JEONG J H,HAN Y C,YANG J H,et al.Waterborne polyurethane modified with poly(ethylene glycol)macromer for waterproof breathable coating[J].Progress in Organic Coatings,2017,103:69-75.
[46] GO C W, YANG J H, KWAK D-S, et al.Waterborne polyurethane modified with silicone macromer and the nylon airbag coated with it[J].Textile Research Journal,2016,86(19):2015-21.
[47] QUAN H,XING J,GU Z.Effects of soft monomers on the water resistance and moisture permeability of hydrophilic polyurethane[J].Journal of Wuhan University of Technology-Mater Sci Ed,2010,25(5):789-794.
[48] SHAO J,WANG C,ZHOU J,et al.Waterproof and moisture permeable coating of polyester fabrics using a novel waterborne polyurethane agent modified with silk fibroin and polyvinylpyrrolidone[J].The Journal of The Textile Institute,2017,108(5):864-869.
[49] LI M,XIAO Y,CHEN Y,et al.Soy protein-modified waterborne polyurethane biocomposites with improved functionality[J].RSC Advances,2016,6(16):12837-12849.
[50] ZHANG H,ZHANG X,QIAN X,et al.Dual-role mechanism of dimethyl sulfone in the preparation of surface layer membrane of superfine fiber veneer synthetic leather[J].Industrial&Engineering Chemistry Research, 2021, 60(47): 17259-17267.
[51] QIANG T,WANG Y,WANG L,et al.Study on the effect of the sanitary properties of microfiber synthetic leather base by using a filling agent[J].Textile Research Journal,2018,88(12):1437-1449.
[52] 任龙芳,王娜,赵国徽,等.皮革涂饰技术在改性超细纤维合成革基布上的应用[J].中国皮革,2013,42(21):11 -14+19.
REN L F,WANG N,ZHAO G H,et al.Application of leather finishing technology on modified microfiber synthetic leather base fabrics[J].China Leather,2013,42(21):11-14+19.(in Chinese)
[53] WU Y,WANG A,ZHENG R,et al.Laser-drilled micro-hole arrays on polyurethane synthetic leather for improvement of water vapor permeability[J].Applied Surface Science,2014,305:1-8.

超细纤维合成革透水汽性能的研究进展

Research Progress of Water Vapor Permeability of Microfiber Synthetic Leather

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	张琦弦, 孙青永, 石碧. 羧基化胶原纤维的制备及其对黄酮苷类化合物的分离特性[J]. 皮革科学与工程, 2023, 33(6): 8-16.
[2]	白忠薛, 王学川, 李彤, 李佳俊, 冯宇宇, 黄梦晨, 岳欧阳, 刘新华. 胶原化学改性及应用进展[J]. 皮革科学与工程, 2023, 33(5): 40-47.
[3]	孙柯璇, 崔玉明, 陈慧, 李飞, 袁鸿昌. 热机械辅助交联改性制备豆粕胶粘剂[J]. 皮革科学与工程, 2023, 33(4): 11-16.
[4]	孙哲, 任松, 方剑, 范浩军, 高强. 氟硅改性无溶剂聚氨酯涂层的制备及性能研究[J]. 皮革科学与工程, 2023, 33(1): 15-20.
[5]	高磊, 牛家嵘, 金欣, 钱晓明, 王闻宇, 林童. 超细纤维合成革柔软改性的研究进展[J]. 皮革科学与工程, 2022, 32(4): 54-59.
[6]	高龙飞, 钱晓明, 王立晶, 朵永超, 唐岚昊. 抗菌型超细纤维合成革复合材料的研究进展[J]. 皮革科学与工程, 2022, 32(1): 40-45.
[7]	张佳星, 王玉增, 陈慧, 单志华. 基于动植物蛋白的生物基塑料研究进展[J]. 皮革科学与工程, 2021, 31(2): 9-15.
[8]	张昕, 范浩军, 李静, 颜俊, 刘爱明, 罗志清. 甲苯减量型超纤含浸用水性聚氨酯的制备与应用性能评价[J]. 皮革科学与工程, 2020, 30(5): 1-8.
[9]	田振华, 王颖. 氧化羧甲基纤维素钠改性胶原膜的制备及表征[J]. 皮革科学与工程, 2020, 30(4): 7-12.
[10]	王岩松;王学川;冯见艳;. 石墨烯的化学改性及其在皮革中的研究进展[J]. , 2017, 27(02): 26-32.
[11]	王之昌;. 水性聚氨酯超细纤维合成革制鞋工艺应用[J]. , 2016, 26(05): 43-47.
[12]	于凤;刘鹏浩;张宗才;何有节;. 兔毛皮染整技术新进展[J]. , 2016, 26(04): 26-.
[13]	肖湾;卢仕;柴玉叶;兰云军;. 苯乙烯-马来酸酐共聚物酯化及产物应用[J]. , 2016, 26(03): 30-34.
[14]	郭学方;彭坤;王芳;范浩军;颜俊;杨涛;叶青平;. 人造革用环保发泡剂的制备及其性能研究[J]. , 2016, 26(02): 20-27.
[15]	尹岳涛;段徐宾;石传晋;李幸;. 蒙脱土的改性及其在制革工业中的应用进展[J]. , 2016, 26(02): 28-34.