层状复合氢氧化物在制革工业中的应用探讨

doi:10.19677/j.issn.1004-7964.2024.02.006

皮革科学与工程 ›› 2024, Vol. 34 ›› Issue (2): 37-46.doi: 10.19677/j.issn.1004-7964.2024.02.006

层状复合氢氧化物在制革工业中的应用探讨

赵嘉敏^1,2,3, 马建中^1,2,3,*, 周永香^1,2,3,*

1.陕西科技大学轻工科学与工程学院（柔性电子学院）,陕西西安 710021;
2.轻化工程国家级实验教学示范中心（陕西科技大学）,陕西西安 710021;
3.西安市绿色化学品与功能材料重点实验室（陕西科技大学）,陕西西安 710021

收稿日期:2023-10-07 修回日期:2023-11-19 接受日期:2023-11-21 出版日期:2024-04-01 上线日期:2024-03-07
通讯作者: *马建中（1960-）,男,教授,主要研究方向为水性高分子的设计与合成、有机/无机纳米复合材料的关键技术、轻纺化学产品的开发与应用等。E-mail：majz@sust.edu.cn。周永香（1976-）,女,副教授,主要研究方向为水性改性胶原材料的设计与合成、胶原蛋白的改性机理等。E-mail：zhouyongxiang@sust.edu.cn。
作者简介:赵嘉敏（1999-）,女,硕士研究生,主要研究方向为基于制革含铬废水制备LDHs材料及其鞣制性能研究。E-mail：3276622356@qq.com。
基金资助:
国家自然科学基金项目（21838007）; 陕西科技大学博士启动基金（2019BJ-13）; 校企合作项目资助（210190131）

Layered Double Hydroxides and their Application in Leather Industry

ZHAO Jiamin^1,2,3, MA Jianzhong^1,2,3,*, ZHOU Yongxiang^1,2,3,*

1. College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science & Technology, Xi’an 710021, China;
2. National Demonstration Center for Experimental Light Chemistry Engineering Education, Shaanxi University of Science & Technology, Xi’an 710021, China;
3. Xi'an Key Laboratory of Green Chemicals and Functional Materials, Shaanxi University of Science & Technology, Xi’an 710021, China

Received:2023-10-07 Revised:2023-11-19 Accepted:2023-11-21 Published:2024-04-01 Online:2024-03-07

摘要/Abstract

摘要： 制革工业是指以动物皮为原材料,经过一系列物理和化学加工生产皮革的产业。传统铬鞣法虽赋予皮革优异的综合性能,但仍存在处理含铬废弃物的环境压力。层状复合氢氧化物（LDHs）是一类由带负电荷的阴离子和带正电荷的金属氢氧化物所构成的层状化合物,具有酸碱性、可调控性、热稳定性和结构记忆效应。文章对LDHs纳米材料的结构及性质进行介绍,并对其在制革工业中作为鞣制材料、复鞣材料、加脂助剂、染色助剂、功能涂饰材料和水处理材料等方面的应用进行了综述。

关键词: 层状复合氢氧化物, 制革工业, 皮革化学品, 水处理

Abstract: The tanning industry refers to the industry of using animal skins as raw materials to produce leather products through a series of physical and chemical treatments. Although traditional chrome tanning method gives leather excellent comprehensive properties, there is still environmental pressure to treat chromium-containing wastes. Layered double hydroxides (LDHs) are a class of layered compounds consisting of negatively charged anions and positively charged metal hydroxides. They have acid-base property and the characteristics of easy modification, thermal stability and structural memory effects. This article introduced the structure and properties of LDHs nanomaterials and reviewed their applications as tanning materials, retanning materials, fatliquoring auxiliaries, dyeing auxiliaries, functional coating materials and water treatment materials in the tanning industry.

Key words: layered double hydroxides, leather industry, leather chemicals, water treatment

中图分类号:

TQ11
TS529.1

赵嘉敏, 马建中, 周永香. 层状复合氢氧化物在制革工业中的应用探讨[J]. 皮革科学与工程, 2024, 34(2): 37-46.

ZHAO Jiamin, MA Jianzhong, ZHOU Yongxiang. Layered Double Hydroxides and their Application in Leather Industry[J]. Leather Science and Engineering, 2024, 34(2): 37-46.

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层状复合氢氧化物在制革工业中的应用探讨

Layered Double Hydroxides and their Application in Leather Industry

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