微乳液皮革脱脂剂的制备及性能研究

doi:10.19677/j.issn.1004-7964.2024.02.003

皮革科学与工程 ›› 2024, Vol. 34 ›› Issue (2): 14-21.doi: 10.19677/j.issn.1004-7964.2024.02.003

微乳液皮革脱脂剂的制备及性能研究

吕斌^1,2,3, 张翎钰^1,2,3, 石传晋⁴, 高党鸽^1,2,3,*, 马建中^1,2,3

1.陕西科技大学轻工科学与工程学院,陕西西安 710021;
2.西安市绿色化学品与功能材料重点实验室,陕西西安 710021;
3.陕西科技大学轻化工程国家级实验教学示范中心,陕西西安 710021;
4.中国皮革和制鞋工业研究院（晋江）有限公司,福建晋江 3622001

收稿日期:2023-08-31 修回日期:2023-11-05 接受日期:2023-11-13 出版日期:2024-04-01 上线日期:2024-03-07
通讯作者: *高党鸽（1982-）,女,博士,教授,主要研究方向：改性胶原纤维用纳米复合材料、功能型高分子的研究。E-mail：dangge2000@126.com。
作者简介:吕斌（1980-）,男,博士,教授,主要研究方向：皮革化学品、油田化学品的研究。E-mail:xianyanglvbin@163.com。
基金资助:
陕西省创新能力支撑计划（2021TD-16）

Study on the Preparation and Performance of Microemulsion Leather Degreasing Agent

LV Bin^1,2,3, ZHANG Lingyu^1,2,3, SHI Chuanjin⁴, GAO Dangge^1,2,3,*, MA Jianzhong^1,2,3

1. School of Light Industry Science and Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China;
2. Xi'an Key Laboratory of Green Chemicals and Functional Materials, Xi'an 710021, China;
3. National Demonstration Center for Experimental Light Chemistry Engineering Education, Shaanxi University of Science & Technology, Xi'an 710021, China;
4. China Leather and Shoe Industry Research Institute (Jinjiang) Co., LTD., Jinjiang 362200, China

Received:2023-08-31 Revised:2023-11-05 Accepted:2023-11-13 Published:2024-04-01 Online:2024-03-07

摘要/Abstract

摘要： 研究了微乳液主表面活性剂种类及配比、助表面活性剂种类、主表面活性剂与助表面活性剂比值及主表面活性剂与D-柠檬烯的比值对伪三相图面积的影响,通过盐度扫描优化了水相中NaCl的用量,获得了微乳液最优制备工艺;通过动态光散射、电导率等对微乳液结构性能进行了表征。结果表明：当脂肪醇聚氧乙烯醚、十二烷基硫酸钠、异构醇醚为主表面活性剂且三者质量比为1∶1∶1,正丁醇为助表面活性剂,主表面活性剂与助表面活性剂的比值为2∶1,主表面活性剂与D-柠檬烯的质量比为2∶1,NaCl用量为4.8%水溶液为水相时,得到的双连续微乳液微乳区面积最大;微乳液的粒径为51.8 nm,多分散指数为0.274,具有较小的粒径及较好的分散性,表面张力为27.3 mN/m,界面张力为0.09 mN/m,乳化、润湿和稳定性能优异;微乳液皮革脱脂剂对多脂绵羊酸皮的脱脂率高于市售皮革脱脂剂。

关键词: 微乳液, 皮革, 脱脂剂, 表面活性剂

Abstract: The effects of microemulsion’s main surfactant type and ratio, co-surfactant type, the ratio of main surfactant to co-surfactant, and the ratio of main surfactant to D-limonene on the area of pseudo-three-phase diagrams were investigated. The optimal preparation process of microemulsion was obtained by optimizing the amount of NaCl in the aqueous phase by salinity scanning. The structural properties of microemulsion were characterized by dynamic light scattering and electrical conductivity. Results showed that the bicontinuous microemulsion with the largest microemulsion area was obtained when the conditions were as follow: fatty alcohol polyoxyethylene ether, sodium dodecyl sulfate and isomeric alcohol ether were used as the main surfactants and their mass ratio was 1∶1∶1; n-butanol was the co-surfactant and the ratio of the main surfactants to the co-surfactant was 2∶1; the mass ratio of the main surfactants to D-limonene was 2∶1, and the aqueous solution with the dosage of NaCl of 4.8% served as the aqueous phase. The microemulsion’s particle size was 51.8 nm and its polydispersity index was 0.274, indicating the smaller particle size and better dispersion. The microemulsion’s surface tension was 27.3 mN/m and its interfacial tension was 0.09 mN/m, and its emulsification, wettability and stability performance were excellent. For the fatty pickled sheep skin, the degreasing rate of the microemulsion leather degreasing agent was higher than that of the commercially available leather degreasing agent.

Key words: microemulsion, leather, degreasing agent, surfactant

中图分类号:

TS529.1

吕斌, 张翎钰, 石传晋, 高党鸽, 马建中. 微乳液皮革脱脂剂的制备及性能研究[J]. 皮革科学与工程, 2024, 34(2): 14-21.

LV Bin, ZHANG Lingyu, SHI Chuanjin, GAO Dangge, MA Jianzhong. Study on the Preparation and Performance of Microemulsion Leather Degreasing Agent[J]. Leather Science and Engineering, 2024, 34(2): 14-21.

参考文献

[1] 王琛. PO封端FMEE在皮革深层脱脂中的应用[J].皮革与化工,2022,39(5):10-14.
WANG C.Application of PO sealing FMEE in deep leather[J].Leather&Chemical Industry,2022,39(5):10-14.(in Chinese)
[2] 范金石,徐桂云.皮革脱脂浅述[J].皮革化工,1997(4):7-12.
FAN J S,XU G Y.Leather stripping shallow description[J].Leather Chemical Industry,1997(4):7-12.(in Chinese)
[3] 吕斌,余亚金,李鹏飞,等.非离子表面活性剂在制革工业中的应用[J].日用化学品科学,2018,41(9):54-60.
LV B,YU Y J,LI P F,et al.Application of nonionic surfactants in the tanning industry[J].Science of Daily Chemicals,2018,41(9):54-60.(in Chinese)
[4] 刘彦,朱玲,陈倩,等.柴油脂肪酶ZG的制革应用性能研究[J].中国皮革,2015,44(5):21-24+28.
LIU Y,ZHU L,CHEN Q,et al.Study on the tanning application performance of diesel lipase ZG[J].Chinese Leather,2015,44(5):21-24+28.(in Chinese)
[5] SUTHAR T, PATEL P,SINGH P, et al.Hesperidin microemulsion: Formulation optimization, characterization, and in vitro evaluation[J].Journal of Drug Delivery Science and Technology,2023,80:104166.
[6] 冯远. 微乳液在制革工业中的应用研究进展[J].皮革与化工,2016,33(4):17-20.
FENG Y.Progress in the application of microemulsion in the tanning industry[J].Leather&Chemical Industry,2016,33(4):17-20.(in Chinese)
[7] 吴欣,孙志高.大豆油微乳液冰浆的制备及其性能研究[J].制冷学报,2023,44(5):139-144+166.
WU X,SUN Z G.Preparation of soybean oil microemulsion ice and its properties[J].Journal of Refrigeration,2023,44(5):139-144+166.(in Chinese)
[8] ZHIPING D,XUEBIN M,XIUMEI T,et al.Preparation and properties of microemulsion detergent with linear medium chain fatty alcohols as oil phase[J].Journal of Molecular Liquids,2016,223:805-810.
[9] 荣鑫. SDBS微乳液的制备及其对石油污染土壤的修复研究[D].沈阳:沈阳建筑大学,2022.
RONG X.Preparation of SDBS microemulsion and remediation of petroleum-contaminated soil[D].Shenyang:Shenyang Jianzhu University,2022.(in Chinese)
[10] GB/T 22237-2008,表面活性剂表面张力的测定[S].
GB/T 22237-2008,Surface active agents--Determination of surface tension[S].(in Chinese)
[11] 赵雅洁,侯吉瑞,屈鸣,等.致密油藏纳米微乳液性能评价与驱油机理分析[J].油田化学,2022,39(2):338-342+354.
ZHAO Y J,HOU J R,QU M,et al.Evaluation of nanoemulsion performance and mechanism analysis of oil flooding[J].Oilfield Chemistry,2022,39(2):338-342+354.(in Chinese)
[12] 谢志辉,刘建中,宁浩良,等.一种O/W型微乳液纳米载体的制备及其对大麻二酚包覆的性能研究[J].日用化学工业,2022,52(5):514-520.
XIE Z H,LIU J Z,NING H L,et al.Preparation of an O/W type microemulsion nanocarrier and its performance against cannabinol coating[J].Daily chemical industry,2022,52(5):514-520.(in Chinese)
[13] GB/T 24368-2009,玻璃表面疏水污染物检测接触角测量法[S].
GB/T 24368-2009,Test method for hydrophobic contamination on glass by contact angle measurement[S].(in Chinese)
[14] 董海波,陈林伟,杨娟,等.一种皮革脱脂剂的开发[J].中国洗涤用品工业,2020(7):103-106.
DONG H B,CHEN L W,YANG J,et al.Development of a leather deasing agent[J].China detergent Industry,2020(7):103-106.(in Chinese)
[15] 薛振华,王儒杰,夏颖帆,等.高效皮革脱脂剂的制备与应用[J].中国皮革,2020,49(7):36-42.
XUE Z H,WANG R J,XIA Y F,et al.Preparation and application of high efficiency leather deasing agents[J].China Leather,2020,49(7):36-42.(in Chinese)
[16] 张峙,胡徐彦,袁辉,等.鼠李糖脂纳米乳液的构建及性能研究[J].日用化学工业,2021,51(11):1067-1072.
ZHANG Z,HU X Y,YUAN H,et al.Construction and properties of rhamnose nanolipid nanoemulsion[J].Daily Chemical industry,2021,51(11):1067-1072.(in Chinese)
[17] 樊文娜,李刚辉,王婷婷,等.(AEO-9/SAS60)/石油醚/醇/水微乳液相行为的研究[J].精细化工,2016,33(7):761-767.
FAN W N,LI G H,WANG T T,et al.(AEO-9/SAS 60)/Study of the behavior of petroleum ether/alcohol/water microemulsion phase[J].Fine Chemical Industry,2016,33(7):761-767.(in Chinese)
[18] 杨晨,韩瑞,孔凡,等.牡丹籽油微乳液的制备及其性质研究[J].中国油脂,2021,46(6):59-64+70.
YANG C,HAN R,KONG F,et al.Preparation of the peony seed oil microemulsions and its properties[J].Chinese Fase,2021,46(6):59-64+70.(in Chinese)
[19] 王娩,陈爽,刘会娥,等.助表面活性剂及油水比对微乳液相行为的影响[J].精细化工,2020,37(8):1645-1652.
WANG M,CHEN S,LIU H E,et al.Effect of auxiliary surfactant and oil to water ratio on microemulsion phase behavior[J].Fine Chemical Industry,2020,37(8):1645-1652.(in Chinese)
[20] 张孝坤. 微乳液增溶性能及其用于含油污泥处理的研究[D].青岛:中国石油大学(华东),2014.
ZHANG X K.Solsolubility of microemulsion and its use for treatment of oily sludge[D].Qingdao:China University of Petroleum(East China),2014.(in Chinese)
[21] 黄志宇,包雨霏,鲁红升,等.突变点检测方法的应用——基于电导渗滤模型的微乳液类型的区分[J].山东化工,2011,40(12):39-42+47.
HUANG Z Y,BAO Y F,LU H S,et al.Application of the mutation point detection method-differentiation of microemulsion types based on the conductive percolation model[J].Shandong Chemical Industry,2011,40(12):39-42+47.(in Chinese)
[22] ZIMING T,YANG Z,CHENG D,et al.Investigation of AOT/ isooctane/water reverse microemulsion system with the presence of different mass ratios of SDS:Conductivity and water solubilization[J].Colloids and Surfaces A:Physicochemi-cal and Engineering Aspects,2022,648:129271.
[23] SCOMOROSCENCO C,TEODORESCU M,NISTOR C L,et al.Preparation and in vitro characterization of alkyl polyglucoside-based microemulsion for topical administration of curcumin[J].Pharmaceutics,2023,15(5):1420.

微乳液皮革脱脂剂的制备及性能研究

Study on the Preparation and Performance of Microemulsion Leather Degreasing Agent

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	王嘉瑞, 马宏瑞, 高骏驰, 郝永永, 朱超. 制革不同工段皮革碎料中铬的稳定性研究[J]. 皮革科学与工程, 2024, 34(2): 7-13.
[2]	赵嘉敏, 马建中, 周永香. 层状复合氢氧化物在制革工业中的应用探讨[J]. 皮革科学与工程, 2024, 34(2): 37-46.
[3]	郑好, 吴晶, 吴芳, 刘文庆. 七巧板原理在可拆卸式皮革包袋造型设计中的应用[J]. 皮革科学与工程, 2024, 34(2): 77-83.
[4]	曾钦宇, 孟凯宁, 王媛麟. 人工智能语境下的皮革制品设计路径研究[J]. 皮革科学与工程, 2024, 34(2): 91-98.
[5]	陈伟长, 柳周青. 家居摆设的皮革材料工艺技法与中国风的审美关系探讨[J]. 皮革科学与工程, 2024, 34(2): 99-105.
[6]	陈晓芬, 董宏坤. 杭州市皮革产业的发展、挑战和应对策略研究（2019~2022）[J]. 皮革科学与工程, 2024, 34(2): 106-110.
[7]	何秀, 张金伟, 周建飞, 曾运航, 张春晓, 税科林, 程海明. 《皮革生产实习》线上线下混合式教学模式探索与实践[J]. 皮革科学与工程, 2024, 34(2): 111-116.
[8]	谢辉, 戴玲. 皮革供应商要素品牌营销策略研究[J]. 皮革科学与工程, 2024, 34(2): 117-122.
[9]	韩明真, 江卓成, 谢果, 曾运航, 王亚楠. 鞣制过程中皮革在转鼓内的形变特征及受力分析[J]. 皮革科学与工程, 2024, 34(1): 1-7.
[10]	金光, 任工昌, 桓源, 洪杰. 基于改进YOLOv5的皮革抓取点识别及定位[J]. 皮革科学与工程, 2024, 34(1): 32-40.
[11]	任可帅, 桑军, 步巧巧, 周建飞, 林炜. 皮革领域“双碳”标准体系的构建研究[J]. 皮革科学与工程, 2024, 34(1): 41-46.
[12]	刘贤军, 单志华. 制革中悬挂式转鼓作用特征[J]. 皮革科学与工程, 2024, 34(1): 47-52.
[13]	龚心悦, 姚云鹤, 谷婷薇, 郑双. 以皮塑为基础的服装立体空间表达探究[J]. 皮革科学与工程, 2024, 34(1): 88-92.
[14]	丁宁, 刘健西. 基于扎根理论的中国皮革制品品牌形象研究[J]. 皮革科学与工程, 2024, 34(1): 119-124.
[15]	刘昊, 宋映, 曾运航, 石碧. 表面活性剂对胰蛋白酶基本性质及制革软化效果的影响[J]. 皮革科学与工程, 2023, 33(6): 1-7.