端氨基超支化聚酰胺高吸收铬鞣助剂的应用研究

doi:10.19677/j.issn.1004-7964.2020.04.006

皮革科学与工程 ›› 2020, Vol. 30 ›› Issue (4): 30-36.doi: 10.19677/j.issn.1004-7964.2020.04.006

端氨基超支化聚酰胺高吸收铬鞣助剂的应用研究

陆曼玲, 邢硕, 刘军, 陈华林^*, 丁克毅

西南民族大学化学与环境保护工程学院,四川成都 610041

收稿日期:2019-11-14 出版日期:2020-08-28 上线日期:2020-07-26
通讯作者: * 陈华林（1972-）,男,教授,aofly@163.com,主要从事皮革化工材料及功能高分子材料研究。
作者简介:陆曼玲（1996-）,女,在读硕士研究生,主要研究方向为功能高分子材料,皮革化工材料。电话134 3849 0510,E-mail:1134818545@qq.com。
基金资助:
国家自然科学基金资助（21776231）; 四川省青年科技创新研究团队专项计划资助项目（2017TD0024）; 西南民族大学2018年中央高校基本科研业务费专项资金资助项目（2018NZD08）

Study on the Application of Amino-Terminated Hyper-Branched Polyamide as High-Exhaustion Chrome Tanning Auxiliary

LU Manling, XING Shuo, LIU Jun, CHEN Hualin^*, DING Keyi

College of Chemistry & Environment Protection Engineering, Southwest Minzu University, Chengdu 610041, China

Received:2019-11-14 Online:2020-08-28 Published:2020-07-26

摘要/Abstract

摘要： 将端氨基超支化聚酰胺（HBPN）作为高吸收铬鞣助剂应用于铬鞣工序中,考察其用量对铬的吸收率、蓝湿革的收缩温度（Ts）、变性温度（Td）和热降解活化能（E）的影响。结果表明,当HBPN的用量为酸皮重的1%时,铬的吸收率可达83.5%,比空白组提高了31.7%。蓝湿革的T_s从97.4 ℃提高到105.9 ℃,T_d从112.47 ℃提高到116.63 ℃,变性焓从129.2 J/g提高到222.7 J/g。基于Flynn-Wall-Ozawa法和Kissinger法的分析结果,蓝湿革的E值分别为169.524~196.668 KJ/mol和153.314 KJ/mol,高于空白组的147.244 KJ/mol。上述研究结果证实,在铬鞣工序中使用HBPN,可以提高铬的吸收率和蓝湿革的湿热稳定性。HBPN是一种具有较高应用潜力的高吸收铬鞣助剂。

关键词: 超支化聚酰胺, 高吸收铬鞣助剂, 铬吸收率, 蓝湿革, 湿热稳定性, 热降解活化能

Abstract: As a new high-exhaustion chrome tanning auxiliary, the amino-terminated hyper-branched polyamide (HBPN) was used in the chrome tanning process of pickled pig hide, and its effect was investigated on the chrome absorptivity, shrinkage temperature (T_s), denaturation temperature (T_d) and thermal degradation active energy (E) of the resulting wet blue, in which the traditional chrome tanning was used as the blank control. Results showed that the addition of 1% HBPN (based on the weight of pickled pig hide) could significantly increase chrome absorptivity to 83.58%, which is 31.7% higher than that of the blank control. At the same time, the Ts, Td and denaturation enthalpy of the obtained wet blue were improved from 97.4 ℃ to 105.9 ℃, 112.47 ℃ to 116.63 ℃ and 129.2 J/g to 222.7 J/g, respectively. The calculatedE values were 169.524-196.668 kJ/mol by Flynn-Wall-Ozawa method and 153.314 kJ/ mol by Kissinger method, respectively, which are higher than 147.244 kJ/mol for the blankcontrol. These results confirm that the use of HBPN in chrome tanning processcan improve thechrome absorptivity and the hydrothermal stability of wet blue, indicating its great application potential as a high-exhaustion chrome tanning auxiliary.

Key words: hyper-branched polyamide, high-exhaustion chrome tanning auxiliary, chrome absorptivity, wet blue, hydrothermal stability, pyrolysisactivation energy

中图分类号:

TS529.1

陆曼玲, 邢硕, 刘军, 陈华林, 丁克毅. 端氨基超支化聚酰胺高吸收铬鞣助剂的应用研究[J]. 皮革科学与工程, 2020, 30(4): 30-36.

LU Manling, XING Shuo, LIU Jun, CHEN Hualin, DING Keyi. Study on the Application of Amino-Terminated Hyper-Branched Polyamide as High-Exhaustion Chrome Tanning Auxiliary[J]. Leather Science and Engineering, 2020, 30(4): 30-36.

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端氨基超支化聚酰胺高吸收铬鞣助剂的应用研究

Study on the Application of Amino-Terminated Hyper-Branched Polyamide as High-Exhaustion Chrome Tanning Auxiliary

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