中空微球制备方法及其制革工业中应用前景

doi:10.19677/j.issn.1004-7964.2022.01.006

皮革科学与工程 ›› 2022, Vol. 32 ›› Issue (1): 34-39.doi: 10.19677/j.issn.1004-7964.2022.01.006

中空微球制备方法及其制革工业中应用前景

张佳星¹, 陈杰², 龙忠珍², 陈慧^1,*, 单志华^1,*

1.四川大学皮革化学与工程教育部重点实验室,四川成都 610065;
2.江苏鸿丰资源循环利用研究院,江苏徐州 629000

收稿日期:2021-07-27 出版日期:2022-02-28 上线日期:2022-01-13
通讯作者: *
作者简介:张佳星（1998-）,男,硕士研究生,E-mail：zjx3199213919@163.com。
基金资助:
徐州江苏鸿丰资源循环利用研究院建设项目（徐科发（2020）76）

Preparation Method of Hollow Microspheres and its Application Prospects in Leather Industry

ZHANG Jiaxing¹, CHEN Jie², LONG Zhongzhen², CHEN Hui^1,*, SHAN Zhihua^1,*

1. Key Laboratory of Leather Chemistry and Engineering, Ministry of Education, Sichuan University, Chengdu 610065,China;
2. Xuzhou Hongfeng Circulation Technology Research Institute, Jiangsu Xuzhou 629000, China

Received:2021-07-27 Published:2022-02-28 Online:2022-01-13

摘要/Abstract

摘要： 中空微球具有质轻、多孔、比表面积大等特点,可以应用于医药、涂料和电池等诸多领域,也是纳米材料研究的热点之一。文章综述了中空微球常见的制备方法与其相关的结构特征,提及了中空微球作为涂料、填充剂和吸附剂在皮革工业的应用,面临现代轻质、高质及环保皮革产品市场迫切诉求,开发皮革领域应用中空微球的潜在意义被表达。

关键词: 中空微球, 轻质, 纳米材料, 制备方法, 皮革工业

Abstract: Hollow microspheres are widely used in medicine, coatings, batteries and other fields because of their light weight, porosity and large specific surface area. It is a research hotspot in the field of nanomaterials. This article reviews the common preparation methods of hollow microspheres and their related structural features, and mentions the application of hollow microspheres as coatings, fillers and adsorbents in the leather industry. Facing the urgent demands of the modern light-weight, high-quality and environmentally-friendly leather product market, the potential significance of developing hollow microspheres in the leather field has been expressed.

Key words: hollow microspheres, light weight, nanomaterials, preparation method, leather industry

中图分类号:

TQ127.2

张佳星, 陈杰, 龙忠珍, 陈慧, 单志华. 中空微球制备方法及其制革工业中应用前景[J]. 皮革科学与工程, 2022, 32(1): 34-39.

ZHANG Jiaxing, CHEN Jie, LONG Zhongzhen, CHEN Hui, SHAN Zhihua. Preparation Method of Hollow Microspheres and its Application Prospects in Leather Industry[J]. Leather Science and Engineering, 2022, 32(1): 34-39.

参考文献

[1] 张昔玉. 酵母菌模板法制备氧化物空心微纳米材料的研究[D].山东科技大学,2017.
[2] 刘一帆. 聚苯乙烯基功能性微球的制备与应用[D].哈尔滨理工大学,2020.
[3] 蔡牧航,魏长平,蔡强.囊泡模板法制备纳米/微米级酚醛树脂中空球[J].吉林大学学报(理学版),2020,58(01):166-170.
[4] Moosavifard S E,Mohammadi A,Darzi M E,et al.A facile strategy to synthesis graphene-wrapped nanoporous copper-cobalt-selenide hollow spheres as an efficient electrode for hybrid supercapacitors[J].Chemical Engineering Journal,2021,415: 128662.
[5] Chen C,Zhang L,Li M,et al.Controlling morphology and particle size of hollow poly(styrene-divinylbenzene)microspheres fabricated by template-based method[J].Journal of Saudi Chemical Society,2018,22(6):644-653.
[6] Zhu Y,Fu J,Zhu L,et al.Preparation of novel hybridinorganic-organic hollow microspheres via aself-template approach[J].Polymer International,2008,57(3):449-453.
[7] Ji X,Zhang H,Bai Z,et al.Self-assembled multifunctional bulk hollow microspheres:Thermal insulation,sound absorption and fire resistance[J].Energy&Buildings,2019,205:109533.
[8] Chen Q,Zhang Y,Ma S,et al.Multishelled NiO/NiCo₂O₄ hollow microspheres derived from bimetal-organic frameworks as high-performance sensing material for acetone detection[J].Journal of Hazardous Materials,2021,415: 125662.
[9] 霍宇平,杨旭东,李忠平,等.二氧化硅中空微球的制备及吸附染料研究[J].硅酸盐通报,2019,38(12):3780-3787.
[10] 巫海燕,李彬,罗文钦,等.SiO₂-CaO-P₂O₅-CoFe₂O₄磁性玻璃陶瓷空心微球的制备及其药物缓释性能研究[J].湖州师范学院学报,2020,42(02):51-56.
[11] Li Y,Wang S,Hao P,et al.Soft-templated formation of double-shelled ZnO hollow microspheres for acetone gas sensing at low concentration/near room temperature[J].Sensors and Actuators B:Chemical,2018,273:751-759.
[12] 蔡牧航,徐囡,刘柱,等.自组装囊泡模板法制备酚醛树脂中空微球[J].功能材料,2019,50(08):8102-8108.
[13] Li Y,Wang Y,Ambreen J,et al.Synthesis of structured hollow microspheres with sandwich-like hybrid shell of RGO/Pd/m-SiO₂ for highly efficient catalysis[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2019,577:129-137.
[14] Zhao K,Ye F,Cheng L,et al.Formation of Ultra-High Temperature Ceramic Hollow Microspheres as Promising Lightweight Thermal Insulation Materials via a Molten Salt-Assisted Template Method[J].ACS applied materials&interfaces, 2021, 13(31):37388-37397.
[15] 王东升,邹瑜斌,肖峰,等.一种磁性微藻基生物炭的制备方法及其应用:CN109876810A[P].2019-03-26.
[16] 王鼎,朱晶心,陈松,等.以丝素蛋白微球为模板制备介孔SiO₂空心微球[J].化工新型材料,2017,45(12):216-220.
[17] 王少华. 软模板法制备形貌规整的中空有机硅微球[D].大连理工大学,2019.
[18] Gao M,Fu J,Wang M,et al.A self-template and self-activation co-coupling green strategy to synthesize high surface area ternary-doped hollow carbon microspheres for high performance supercapacitors[J].Journal of Colloid and Interface Science,2018,524:165-176.
[19] 沈明虎,姚秉华,鲁盼,等.无模板一步水热法制备TiO2中空微球及其光催化性能[J].化学研究与应用,2019,31(07):1242-1248.
[20] 黄冠华,刘序彦,房晨曦,等.生物模板法制备磁性中空微球的方法和应用[J].化工进展,2021,40(05):2613-2623.
[21] Denga W,Guoa H C,Lia G A,et al.Fabrication of polymeric-Laponite composite hollow microspheres via LBL assembly[J].Chinese Chemical Letters,2017,28(2):367-371.
[22] 段涛,张力,聂冬梅,等.基于动态溶胀法制备中空聚合物微球[J].强激光与粒子束,2012,24(02):361-364.
[23] 张帆. 酪素基中空纳米复合乳液的制备与性能研究[D].陕西科技大学,2017.
[24] Chen P,Ye N,He C,et al.Preparation of Polyacrylate Hollow Microspheres via Facile Spray Drying[J].Applied Sciences,2019,9(2):228.
[25] Zhang C,Chen G,Zhang R,et al.Charge modulation of CNTs-based conductive network for oxygen reduction reaction and microwave absorption[J].Carbon,2021,178:310-319.
[26] Maciejewska M,Gawdzik B,Rogulska M.Regular Polymeric Microspheres with Highly Developed Internal Structure and Remarkable Thermal Stability[J].Materials,2021,14(9):2240-2240.
[27] Liu H,Bu Y,Du J,et al.Preparation of hollow ceramic microspheres utilized as a carrier for additive delivery in cement[J].Materials Letters,2021,300:130157.
[28] Rogers J A,Bao Z.Printed plastic electronics and paper-like displays[J].Journal of Polymer Science Part A-Polymer Chemistry,2002,40(20):3327-3334.
[29] 房毅. 彩色纳米中空微球的制备及其应用研究[D].天津大学,2014.
[30] Paultre A L.Plastic display demonstrates electronic-ink practically[J].Electronic Products Magazine,2001,48(3):23-29.
[31] 孙静,程建丽,魏德卿.聚合物微球在皮革涂饰中的应用[J].皮革科学与工程,2006,16(02):48-49+57.
[32] 康巧玲. 保温隔热中空微球的制备及其在聚丙烯酸酯中的应用研究[D].陕西科技大学,2018.
[33] Li H,Li Q,Liu H,et al.Ice-resistant surface with three dimensional spherical halloysite aerogel:Construction and anti-icing mechanism[J].Ceramics International,2021,47(16):22976-22984.
[34] 蔡佳文. 缓释自修复微球的制备及在涂层中的应用[D].浙江大学,2020.
[35] 孙飞龙. 皮革废水处理中絮凝沉降工艺的改进探讨[J].皮革制作与环保科技,2020,1(03):44-48.
[36] 丁海燕,张贝贝,李运,等.新型吸附材料与制革废水处理[J].皮革科学与工程,2020,30(04):17-23.
[37] 栾俊,王全杰,王闪闪,等.微生物处理制革废弃物研究进展[J].皮革科学与工程,2015,25(06):28-33.
[38] Wu X P,Cheng L,Song C S,et al.Constructing carbon-coated Fe₃O₄ hierarchical microstructures with a porous structure and their excellent Cr(VI)ion removal properties[J].Journal of Materials Science:Materials in Electronics,2021,32:20844-20855.
[39] 孙凌凌,俞从正,马兴元.印染废水处理技术在皮革染色废水处理中的应用[J].皮革科学与工程,2009,19(5):49-53.
[40] Fang X,Wu P,Fu J.Facile construction of N,P and O ternary self-doped hollow carbon microspheres with hierarchical porous structure for environmental applications[J].Microporous and Mesoporous Materials,2021,321:111135.
[41] 虞德胜,杜金霞,谭然,等.丙烯酸酯类两亲聚合物的三元乳液共聚制备及其复鞣加脂性能[J].皮革科学与工程,2020,30(03):1-6+34.
[42] 魏德卿,刘宗惠,孙永进,等.HMP中空微球聚合物在复鞣中的应用特性[J].中国皮革,1997,26(04):7-8.

中空微球制备方法及其制革工业中应用前景

Preparation Method of Hollow Microspheres and its Application Prospects in Leather Industry

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 3

编辑推荐

Metrics

本文评价

[1]	石佳博, 张睿祯, 盛理, 刘强. 生物大分子基纳米复合功能膜的制备及应用研究进展[J]. 皮革科学与工程, 2023, 33(3): 24-30.
[2]	龙燕茹, 刘月, Carmen Gaidau, 辜海彬, . 微波辐照在皮革工业中的应用研究现状[J]. 皮革科学与工程, 2019, 29(05): 33-.
[3]	程书强, 罗娟, . 基于人工神经网络的皮革生态评价[J]. 皮革科学与工程, 2019, 29(02): 44-46.