制革污泥生物炭对废水中亚甲基蓝的吸附性能研究

doi:10.19677/j.issn.1004-7964.2021.06.003

皮革科学与工程 ›› 2021, Vol. 31 ›› Issue (6): 14-20.doi: 10.19677/j.issn.1004-7964.2021.06.003

制革污泥生物炭对废水中亚甲基蓝的吸附性能研究

周波¹, 穆传辉¹, 唐余玲¹, 周建飞^1,2,*

1.四川大学制革清洁技术国家工程研究中心,四川成都 610065;
2.四川大学皮革化学与工程教育部重点实验室,四川成都 610065

收稿日期:2021-05-24 出版日期:2021-12-28 上线日期:2021-11-25
通讯作者: *周建飞（1978-）,男,博士,教授,zhouamao2004@126.com,主要从事制革清洁技术、污染物防控技术。
作者简介:周波（1997-）,男,硕士研究生,followyournature@163.com。
基金资助:
国家重点研发计划（2017YFB0308500）

Study on the Adsorption Performance of Tannery Sludge Biochar Towards Methylene Blue from Wastewater

ZHOU Bo¹, MU Chuanhui¹, TANG Yuling¹, ZHOU Jianfei^1,2,*

1. National Engineering Research Center of Clean Technology in Leather Industry,, Sichuan University, Chengdu 610065, China;
2. The Key Laboratory of Leather Chemistry and Engineering of Ministry of Education, Sichuan University, Chengdu 610065, China

Received:2021-05-24 Online:2021-12-28 Published:2021-11-25

摘要/Abstract

摘要： 以制革污泥为原料,在氮气氛围下,控制热解温度在300~700 ℃范围内,制备了污泥基生物炭（TSBC）,并研究了其对亚甲基蓝染料（MB）的吸附效果及机理。结果表明,500 ℃下热解得到的生物炭TSBC₅₀₀,比表面积最大,为40.98 m²/g,其平均孔径是9.21 nm,且表面存在大量-OH、-COOH等含氧官能团。相较于其他温度热解得到的生物炭,TSBC₅₀₀对MB的吸附去除率最高。吸附行为符合拟二级动力学模型与Langmuir热力学模型,吸附过程为主要受化学吸附控制的单分子层吸附。TSBC₅₀₀对MB的最大吸附容量可达76.34 mg/g。结合FTIR分析发现,TSBC₅₀₀对MB的吸附主要是静电作用、氢键作用、离子交换和π-π EDA等共同作用的结果。

关键词: 制革污泥, 生物炭, 亚甲基蓝, 吸附

Abstract: Tannery sludge was used as raw material to prepare the biochar (TSBC) by traditional pyrolysis method under a nitrogen atmosphere, and the adsorption performance and mechanism of TSBC were studied using methylene blue (MB) as model pollutant. The results indicated that the properties reached the maximum at 500 ℃. The specific surface area and average pore diameter of TSBC₅₀₀ were 40.98 m²/g and 9.21 nm, respectively, and a large number of oxygen-containing functional groups such as -OH and -COOH were formed on the surface. Compared with the TSBC obtained under other pyrolysis temperatures, TSBC₅₀₀ showed the superior removal efficiency of MB (92.3%), and the maximum adsorption capacity reached up to 76.34 mg/g. Besides, the adsorption process of MB was in accordance with a pseudo-second-order kinetics and the Langmuir isotherm well. Combined with FTIR analysis, the adsorption mechanism of TSBC₅₀₀ on MB was mainly dependent on the electrostatic attraction, hydrogen-bond interaction, ion exchange, π-π EDA.

Key words: tannery sludge, biochar, methylene blue, adsorption

中图分类号:

X794

周波, 穆传辉, 唐余玲, 周建飞. 制革污泥生物炭对废水中亚甲基蓝的吸附性能研究[J]. 皮革科学与工程, 2021, 31(6): 14-20.

ZHOU Bo, MU Chuanhui, TANG Yuling, ZHOU Jianfei. Study on the Adsorption Performance of Tannery Sludge Biochar Towards Methylene Blue from Wastewater[J]. Leather Science and Engineering, 2021, 31(6): 14-20.

参考文献

[1] Barka N, Abdennouri M, Makhfouk M E.Removal of Methylene Blue and Eriochrome Black T from aqueous solutions by biosorption on Scolymus hispanicus L.: Kinetics, equilibrium and thermodynamics[J]. Journal of the Taiwan Institute of Chemical Engineers, 2010, 42(2): 320-326.
[2] 秦彬,谷晋川,殷萍,等.染料废水处理技术研究进展[J].化工环保,2021,41(1):9-18.
[3] Hosny A, Saied E, Hasanin M.Green and ecofriendly bio-removal of methylene blue dye from aqueous solution using biologically activated banana peel waste[J]. Sustainable Chemistry and Pharmacy, 2020, 18: 100333.
[4] 李玉梅,王畅,张连科,等.生物炭/铁酸镧磁性复合材料的制备及对亚甲基蓝的吸附性能[J].环境污染与防治,2020,42(7):826-832.
[5] Shi C, Tao F, Cui Y.Evaluation of nitriloacetic acid modified cellulose film on adsorption of methylene blue[J]. International Journal of Biological Macromolecules, 2018, 114: 400-407.
[6] Tansir A, Mu N, Gaber E, et al.Effective and fast adsorptive removal of toxic cationic dye (MB) from aqueous medium using amino-functionalized magnetic multiwall carbon nanotubes[J]. Journal of Molecular Liquids, 2019, 282: 154-161.
[7] Tong D S, Wu C W, Adebajo M O, et al.Adsorption of methylene blue from aqueous solution onto porous cellulose-derived carbon/montmorillonite nanocomposites[J]. Applied Clay Science, 2018, 161: 256-264.
[8] 孙兰梅,孙宇明,李明阳,等.各种吸附材料对亚甲基蓝废水处理的研究[J].山东化工,2018,47(14):197-198.
[9] Binh Q A, Nguyen H H.Investigation the isotherm and kinetics of adsorption mechanism of herbicide 2,4- dichlorophenoxyacetic acid (2, 4-D) on corn cob biochar[J]. Bioresource Technology Reports, 2020, 11: 100520.
[10] 常飞,程文博,张天旭.生物炭吸附去除水中有机污染物的研究进展[J].能源研究与信息,2018,34(4):187-194.
[11] Zhai S M, Li M, Xiong Y H, et al.Dual resource utilization for tannery sludge: Effects of sludge biochars (BCs) on volatile fatty acids (VFAs) production from sludge anaerobic digestion.[J]. Bioresource technology, 2020, 316: 123903.
[12] Jessieleena A A, Priyanka M, Saravanakumar M P.Comparative study of Fenton, Fe²+/NaOCl and Fe²+/(NH₄)₂S₂O₈ on tannery sludge dewaterability, degradability of organics and leachability of chromium[J]. Journal of Hazardous Materials, 2021, 402: 123495.
[13] 王学川,程正平,丁志文,等.我国危险废物管理制度与含铬皮革废料的管理现状及建议[J].皮革科学与工程,2020,30(02):42-47.
[14] Swarnalatha S, Ramani K, Karthi A G, et al.Starved air combustion-solidification/stabilization of primary chemical sludge from a tannery[J].Journal of Hazardous Materials, 2006, 137(1): 304-313.
[15] 龚英. 热处理有毒制革污泥的固化/稳定化[J].西部皮革,2008,(14):47-53.
[16] Tan X F, Liu Y G, Zeng G M, et al.Application of biochar for the removal of pollutants from aqueous solutions[J]. Chemosphere, 2015, 125: 70-85.
[17] Chen T, Zhang Y, Wang H T, et al.Influence of pyrolysis temperature on characteristics and heavy metal adsorptive performance of biochar derived from municipal sewage sludge[J]. Bioresource Technology, 2014, 164: 47-54.
[18] 程国淡,黄青,张凯松.热解温度和时间对生物干化污泥生物炭性质的影响[J].环境工程学报,2013,7(3):1133-1138.
[19] Sahu S, Pahi S, Tripathy S, et al.Adsorption of methylene blue on chemically modified lychee seed biochar: Dynamic, equilibrium, and thermodynamic study[J]. Journal of Molecular Liquids, 2020, 315: 113743.
[20] 潘界舟,宋寒冰,王盛华,等.聚丙烯酸-羧甲基壳聚糖水凝胶对皮革废水中Cr(Ⅲ)吸附研究[J].皮革科学与工程,2019,29(3):12-18.
[21] 张明月,李锋民,卢伦,等.芦苇生物炭对亚甲基蓝的吸附特性研究[J].中国海洋大学学报(自然科学版),2016,46(12):96-103.
[22] Jh A, Hg B, Nm A, et al.Removal of methylene blue from aqueous solutions by biochar prepared from the pyrolysis of mixed municipal discarded material[J]. Science of the Total Environment, 2020, 714: 136832.
[23] Yenisoy-Karaka S, A Aygün, Güne M, et al. Physical and chemical characteristics of polymer-based spherical activated carbon and its ability to adsorb organics[J]. Carbon, 2004, 42(3): 477-84.
[24] Fan S S, Wang Y, Wang Z, et al.Removal of methylene blue from aqueous solution by sewage sludge-derived biochar: Adsorption kinetics, equilibrium, thermodynamics and mechanism[J]. Journal of Environmental Chemical Engineering, 2017, 5(1): 601-611.
[25] 袁健,钱雅洁,薛罡,等.活性污泥水热碳化法制备磁性炭及对水体Cd²+及Pb²+的去除[J].环境工程,2020,38(2):55-62.
[26] Jang H M, Yoo S, Choi Y K, et al.Adsorption isotherm, kinetic modeling and mechanism of tetracycline on Pinus taeda-derived activated biochar[J]. Bioresource Technology, 2018, 259: 24-31.
[27] Fan S S, Tang J, Wang Y, et al.Biochar prepared from co-pyrolysis of municipal sewage sludge and tea waste for the adsorption of methylene blue from aqueous solutions: Kinetics, isotherm, thermodynamic and mechanism[J]. Journal of Molecular Liquids, 2016, 220: 432-441.

制革污泥生物炭对废水中亚甲基蓝的吸附性能研究

Study on the Adsorption Performance of Tannery Sludge Biochar Towards Methylene Blue from Wastewater

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	李佶衡, 彭良琼, 郭丽君, 张文华. 固液吸附等温线模型与热力学参数计算[J]. 皮革科学与工程, 2023, 33(6): 36-43.
[2]	彭良琼, 林诗雨, 郭丽君, 张文华, 石碧, 廖学品. 含铬革屑负载亚铁氰化铜钾对铯的快速吸附[J]. 皮革科学与工程, 2023, 33(5): 8-15.
[3]	唐余玲, 郭丽君, 周建飞, 石碧. 含铬革屑生物炭活化过硫酸盐降解亚甲基蓝[J]. 皮革科学与工程, 2023, 33(4): 1-6.
[4]	党旭岗, 尚嘉瑶, 宋雅琴, 王学川, 岳旭航, 石小华. 制革废弃皮胶原-多聚糖复合材料吸附剂的研究进展[J]. 皮革科学与工程, 2023, 33(4): 41-46.
[5]	单超群, 马宏瑞, 朱超, 王河有, 王慧琴. 有机分子聚合过程中DOM特征及其与蒙脱土的吸附过程[J]. 皮革科学与工程, 2023, 33(2): 8-14.
[6]	强涛涛, 邱波强, 朱润桐. 氧化石墨烯/多孔SiO₂微球复合材料的吸附性能研究[J]. 皮革科学与工程, 2023, 33(2): 28-33.
[7]	党靖雯, 马宏瑞, 朱超, 徐芝芬, 周姣. 制革废水中含铬有机物的生物吸附-矿化协同去除机制[J]. 皮革科学与工程, 2023, 33(1): 9-14.
[8]	张宗惠, 王芳, 胡亚迪, 刘捷, 汤克勇. 制革污泥热解特性的研究——基于分布活化能模型和TG-FTIR-MS联用[J]. 皮革科学与工程, 2022, 32(2): 14-20.
[9]	杨盼, 强西怀. TWLZ复鞣对TWS鞣革纤维吸附栲胶性能的影响[J]. 皮革科学与工程, 2022, 32(1): 27-33.
[10]	郑顺姬, 隋智慧, 曹向禹. 角蛋白基吸附剂的研究进展[J]. 皮革科学与工程, 2022, 32(1): 46-52.
[11]	刘素清, 修绍迪, 王玉路, 张斐斐, 靳丽强. 明胶/聚乙烯胺凝胶珠的制备及其对Cr(Ⅵ)/ Cu(Ⅱ)的吸附性能[J]. 皮革科学与工程, 2021, 31(4): 22-26.
[12]	梁姣利. 氧化石墨烯/壳聚糖复合材料的制备及吸附应用研究进展[J]. 皮革科学与工程, 2021, 31(3): 30-35.
[13]	孙绪兵, 高天, 由耀辉. 单宁酸铁和单宁酸亚铁对磷的吸附特性[J]. 皮革科学与工程, 2020, 30(5): 9-15.
[14]	丁海燕, 张贝贝, 李运, 王全杰. 新型吸附材料与制革废水处理[J]. 皮革科学与工程, 2020, 30(4): 17-23.
[15]	马宏瑞, 李晓洁, 陈丰羽, 朱超, 王晴, 陈湘萍, 黄彬. 超声辅助酸淋洗对制革污泥Cr的浸出及形态转化影响研究[J]. 皮革科学与工程, 2020, 30(1): 7-12.