微乳液皮革脱脂剂的制备及性能研究

doi:10.19677/j.issn.1004-7964.2024.02.003

Leather Science and Engineering ›› 2024, Vol. 34 ›› Issue (2): 14-21.doi: 10.19677/j.issn.1004-7964.2024.02.003

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Study on the Preparation and Performance of Microemulsion Leather Degreasing Agent

LV Bin^1,2,3, ZHANG Lingyu^1,2,3, SHI Chuanjin⁴, GAO Dangge^1,2,3,*, MA Jianzhong^1,2,3

1. School of Light Industry Science and Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China;
2. Xi'an Key Laboratory of Green Chemicals and Functional Materials, Xi'an 710021, China;
3. National Demonstration Center for Experimental Light Chemistry Engineering Education, Shaanxi University of Science & Technology, Xi'an 710021, China;
4. China Leather and Shoe Industry Research Institute (Jinjiang) Co., LTD., Jinjiang 362200, China

Received:2023-08-31 Revised:2023-11-05 Accepted:2023-11-13 Published:2024-04-01 Online:2024-03-07

Abstract

Abstract: The effects of microemulsion’s main surfactant type and ratio, co-surfactant type, the ratio of main surfactant to co-surfactant, and the ratio of main surfactant to D-limonene on the area of pseudo-three-phase diagrams were investigated. The optimal preparation process of microemulsion was obtained by optimizing the amount of NaCl in the aqueous phase by salinity scanning. The structural properties of microemulsion were characterized by dynamic light scattering and electrical conductivity. Results showed that the bicontinuous microemulsion with the largest microemulsion area was obtained when the conditions were as follow: fatty alcohol polyoxyethylene ether, sodium dodecyl sulfate and isomeric alcohol ether were used as the main surfactants and their mass ratio was 1∶1∶1; n-butanol was the co-surfactant and the ratio of the main surfactants to the co-surfactant was 2∶1; the mass ratio of the main surfactants to D-limonene was 2∶1, and the aqueous solution with the dosage of NaCl of 4.8% served as the aqueous phase. The microemulsion’s particle size was 51.8 nm and its polydispersity index was 0.274, indicating the smaller particle size and better dispersion. The microemulsion’s surface tension was 27.3 mN/m and its interfacial tension was 0.09 mN/m, and its emulsification, wettability and stability performance were excellent. For the fatty pickled sheep skin, the degreasing rate of the microemulsion leather degreasing agent was higher than that of the commercially available leather degreasing agent.

Key words: microemulsion, leather, degreasing agent, surfactant

CLC Number:

TS529.1

LV Bin, ZHANG Lingyu, SHI Chuanjin, GAO Dangge, MA Jianzhong. Study on the Preparation and Performance of Microemulsion Leather Degreasing Agent[J]. Leather Science and Engineering, 2024, 34(2): 14-21.

References

[1] 王琛. PO封端FMEE在皮革深层脱脂中的应用[J].皮革与化工,2022,39(5):10-14.
WANG C.Application of PO sealing FMEE in deep leather[J].Leather&Chemical Industry,2022,39(5):10-14.(in Chinese)
[2] 范金石,徐桂云.皮革脱脂浅述[J].皮革化工,1997(4):7-12.
FAN J S,XU G Y.Leather stripping shallow description[J].Leather Chemical Industry,1997(4):7-12.(in Chinese)
[3] 吕斌,余亚金,李鹏飞,等.非离子表面活性剂在制革工业中的应用[J].日用化学品科学,2018,41(9):54-60.
LV B,YU Y J,LI P F,et al.Application of nonionic surfactants in the tanning industry[J].Science of Daily Chemicals,2018,41(9):54-60.(in Chinese)
[4] 刘彦,朱玲,陈倩,等.柴油脂肪酶ZG的制革应用性能研究[J].中国皮革,2015,44(5):21-24+28.
LIU Y,ZHU L,CHEN Q,et al.Study on the tanning application performance of diesel lipase ZG[J].Chinese Leather,2015,44(5):21-24+28.(in Chinese)
[5] SUTHAR T, PATEL P,SINGH P, et al.Hesperidin microemulsion: Formulation optimization, characterization, and in vitro evaluation[J].Journal of Drug Delivery Science and Technology,2023,80:104166.
[6] 冯远. 微乳液在制革工业中的应用研究进展[J].皮革与化工,2016,33(4):17-20.
FENG Y.Progress in the application of microemulsion in the tanning industry[J].Leather&Chemical Industry,2016,33(4):17-20.(in Chinese)
[7] 吴欣,孙志高.大豆油微乳液冰浆的制备及其性能研究[J].制冷学报,2023,44(5):139-144+166.
WU X,SUN Z G.Preparation of soybean oil microemulsion ice and its properties[J].Journal of Refrigeration,2023,44(5):139-144+166.(in Chinese)
[8] ZHIPING D,XUEBIN M,XIUMEI T,et al.Preparation and properties of microemulsion detergent with linear medium chain fatty alcohols as oil phase[J].Journal of Molecular Liquids,2016,223:805-810.
[9] 荣鑫. SDBS微乳液的制备及其对石油污染土壤的修复研究[D].沈阳:沈阳建筑大学,2022.
RONG X.Preparation of SDBS microemulsion and remediation of petroleum-contaminated soil[D].Shenyang:Shenyang Jianzhu University,2022.(in Chinese)
[10] GB/T 22237-2008,表面活性剂表面张力的测定[S].
GB/T 22237-2008,Surface active agents--Determination of surface tension[S].(in Chinese)
[11] 赵雅洁,侯吉瑞,屈鸣,等.致密油藏纳米微乳液性能评价与驱油机理分析[J].油田化学,2022,39(2):338-342+354.
ZHAO Y J,HOU J R,QU M,et al.Evaluation of nanoemulsion performance and mechanism analysis of oil flooding[J].Oilfield Chemistry,2022,39(2):338-342+354.(in Chinese)
[12] 谢志辉,刘建中,宁浩良,等.一种O/W型微乳液纳米载体的制备及其对大麻二酚包覆的性能研究[J].日用化学工业,2022,52(5):514-520.
XIE Z H,LIU J Z,NING H L,et al.Preparation of an O/W type microemulsion nanocarrier and its performance against cannabinol coating[J].Daily chemical industry,2022,52(5):514-520.(in Chinese)
[13] GB/T 24368-2009,玻璃表面疏水污染物检测接触角测量法[S].
GB/T 24368-2009,Test method for hydrophobic contamination on glass by contact angle measurement[S].(in Chinese)
[14] 董海波,陈林伟,杨娟,等.一种皮革脱脂剂的开发[J].中国洗涤用品工业,2020(7):103-106.
DONG H B,CHEN L W,YANG J,et al.Development of a leather deasing agent[J].China detergent Industry,2020(7):103-106.(in Chinese)
[15] 薛振华,王儒杰,夏颖帆,等.高效皮革脱脂剂的制备与应用[J].中国皮革,2020,49(7):36-42.
XUE Z H,WANG R J,XIA Y F,et al.Preparation and application of high efficiency leather deasing agents[J].China Leather,2020,49(7):36-42.(in Chinese)
[16] 张峙,胡徐彦,袁辉,等.鼠李糖脂纳米乳液的构建及性能研究[J].日用化学工业,2021,51(11):1067-1072.
ZHANG Z,HU X Y,YUAN H,et al.Construction and properties of rhamnose nanolipid nanoemulsion[J].Daily Chemical industry,2021,51(11):1067-1072.(in Chinese)
[17] 樊文娜,李刚辉,王婷婷,等.(AEO-9/SAS60)/石油醚/醇/水微乳液相行为的研究[J].精细化工,2016,33(7):761-767.
FAN W N,LI G H,WANG T T,et al.(AEO-9/SAS 60)/Study of the behavior of petroleum ether/alcohol/water microemulsion phase[J].Fine Chemical Industry,2016,33(7):761-767.(in Chinese)
[18] 杨晨,韩瑞,孔凡,等.牡丹籽油微乳液的制备及其性质研究[J].中国油脂,2021,46(6):59-64+70.
YANG C,HAN R,KONG F,et al.Preparation of the peony seed oil microemulsions and its properties[J].Chinese Fase,2021,46(6):59-64+70.(in Chinese)
[19] 王娩,陈爽,刘会娥,等.助表面活性剂及油水比对微乳液相行为的影响[J].精细化工,2020,37(8):1645-1652.
WANG M,CHEN S,LIU H E,et al.Effect of auxiliary surfactant and oil to water ratio on microemulsion phase behavior[J].Fine Chemical Industry,2020,37(8):1645-1652.(in Chinese)
[20] 张孝坤. 微乳液增溶性能及其用于含油污泥处理的研究[D].青岛:中国石油大学(华东),2014.
ZHANG X K.Solsolubility of microemulsion and its use for treatment of oily sludge[D].Qingdao:China University of Petroleum(East China),2014.(in Chinese)
[21] 黄志宇,包雨霏,鲁红升,等.突变点检测方法的应用——基于电导渗滤模型的微乳液类型的区分[J].山东化工,2011,40(12):39-42+47.
HUANG Z Y,BAO Y F,LU H S,et al.Application of the mutation point detection method-differentiation of microemulsion types based on the conductive percolation model[J].Shandong Chemical Industry,2011,40(12):39-42+47.(in Chinese)
[22] ZIMING T,YANG Z,CHENG D,et al.Investigation of AOT/ isooctane/water reverse microemulsion system with the presence of different mass ratios of SDS:Conductivity and water solubilization[J].Colloids and Surfaces A:Physicochemi-cal and Engineering Aspects,2022,648:129271.
[23] SCOMOROSCENCO C,TEODORESCU M,NISTOR C L,et al.Preparation and in vitro characterization of alkyl polyglucoside-based microemulsion for topical administration of curcumin[J].Pharmaceutics,2023,15(5):1420.

Study on the Preparation and Performance of Microemulsion Leather Degreasing Agent

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