胶原降解物制备表面活性剂能的研究

doi:10.19677/j.issn.1004-7964.2019.04.009

皮革科学与工程 ›› 2019, Vol. 29 ›› Issue (04): 44-49.doi: 10.19677/j.issn.1004-7964.2019.04.009

胶原降解物制备表面活性剂能的研究

李运¹,姜晨辉¹,丁海燕^1,^*(),郭敏²,王全杰¹

^1. 烟台大学化学化工学院,山东烟台 264005
^2. 山东省皮革工业研究所,山东济南 250021

收稿日期:2019-03-26 出版日期:2019-08-28 上线日期:2019-09-09
通讯作者: 丁海燕 E-mail:hyding2970@126.com
作者简介:李运,（1985-）,女,江苏海门市,讲师,主要从事皮革固体废弃物的综合利用,邮箱：liyun605@126.com。
基金资助:
山东省自然科学基金联合专项(ZR2015BL026)

Preparation and Properties of Amino Acid Surfactants with Different Lipophilic Groups

LI Yun¹,JIANG Chenhui¹,DING Haiyan^1,^*(),GUO Min²,WANG Quanjie¹

^1. School of Chemistry and Chemical Engineering, Yantai University, Yantai 264005,China
^2. Shandong Province Leather Industrial Research Institute, Jinan 250021, China

Received:2019-03-26 Online:2019-08-28 Published:2019-09-09
Contact: DING Haiyan E-mail:hyding2970@126.com

摘要/Abstract

摘要：

将胶原蛋白水解物与不同碳链长度的酰氯进行反应,制备了一系列不同碳链长度的CxLS表面活性剂;根据反应后产物中的游离氨基转化率确定最佳反应条件。通过FT-IR对CxLS的结构进行表征,同时测定了CxLS溶液的表面张力、起泡性和泡沫稳定性等参数。结果表明：合成CxLS的最佳反应pH值为9,乙酸乙酯与月桂酰氯的体积比为2:1,反应温度为60 ℃,转化率最高为77.9%。随着酰氯的碳链长度增加,CxLS中游离氨基含量下降,泡沫稳定性增加。酰氯碳链长度为12的月桂酰基CxLS具有最低的表面张力和良好的泡沫稳定性。

关键词: 胶原降解物, 表面活性剂, 酰氯, 转化率, 表面活性

Abstract:

The collagen hydrolysate was prepared by waste leather shavings via alkali hydrolysis.According to Schotten-Baumann reaction, varied collagen hydrolysate-based amino acid surfactants were prepared with collagen hydrolysate and different kinds of acyl chloride with different carbon chain length . The optimal reaction conditions were determined by the free amino content in surfactant solution. The structures of amino acid surfactants were evaluated by Fourier transform infrared spectroscopy analyses (FT-IR). Their physicochemical properties, such as surface tension, foaming and foam stability were investigated. It can be obtained that the reaction pH value was 9, the volume ratio of ethyl acetate to lauroyl chloride was 2:1, the reaction temperature was 60 ℃ and the highest conversion rate was 77.9%. As carbon chain length of acyl chloride increasing, the free amino content in surfactants declined, and their foam stability increased. Lauroyl surfactant with C1₂ has the lowest surface tension and highest foaming stability.

Key words: collagen degradation, surfactant, acyl chloride, transformation rate, surface activity

中图分类号:

TS529.1

李运,姜晨辉,丁海燕,郭敏,王全杰. 胶原降解物制备表面活性剂能的研究[J]. 皮革科学与工程, 2019, 29(04): 44-49.

LI Yun,JIANG Chenhui,DING Haiyan,GUO Min,WANG Quanjie. Preparation and Properties of Amino Acid Surfactants with Different Lipophilic Groups[J]. Leather Science and Engineering, 2019, 29(04): 44-49.

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胶原降解物制备表面活性剂能的研究

Preparation and Properties of Amino Acid Surfactants with Different Lipophilic Groups

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