Fe(III)-Al2O3对制革生化尾水中DOM的去除规律研究

doi:10.19677/j.issn.1004-7964.2019.04.005

Leather Science and Engineering ›› 2019, Vol. 29 ›› Issue (04): 24-29.doi: 10.19677/j.issn.1004-7964.2019.04.005

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Adsorption of Dissolved Organic Matter in Biochemical Tail Water by Fe(III)-Al₂O₃

WANG Qing,MA Hongrui(),HAO Yongyong,ZHU Chao

School of Environmental Science and Engineering,Shaanxi university of science & technology, Xi'an 710021,China

Received:2019-03-28 Published:2019-08-28 Online:2019-09-09
Contact: MA Hongrui E-mail:mahrxingfeng@163.com

Abstract

Abstract:

The removal efficiency of dissolved organic matter (DOM) in secondary effluent by Al₂O₃ and Fe(III)-Al₂O₃ was compared, and the SEM and XRD were used to analyse the changes in structure and composition of Al₂O₃ and Fe(III)-Al₂O₃. While the UV parameters and three-dimensional fluorescence spectroscopy were used to characterize the changes of DOM. The results showed that the removal efficiency of Al₂O₃ was improved remarkably after modification. When the sintering temperature was 150 ℃ and the dosage of Fe(III)-Al₂O₃ was 30 g, the removal rate of chroma was 93.8%. While the removal rate of dissolved organic carbon (DOC) was 38.7%. Fe(III)-Al₂O₃ had many pore structures and loaded with iron hydrous oxides on the surface, which had stronger adsorption capacity for aromatic compounds with high molecular weight and oxygen-containing functional groups. It selectively adsorbed humic-like and fulvic-like substances, which could provide a targeted advanced treatment technology for secondary effluent in tannery wastewater combined with advanced oxidation processes.

Key words: Fe(III)-Al₂O₃, tannery wastewater, secondary effluent, dissolved organic matter

CLC Number:

X794

WANG Qing,MA Hongrui,HAO Yongyong,ZHU Chao. Adsorption of Dissolved Organic Matter in Biochemical Tail Water by Fe(III)-Al₂O₃[J]. Leather Science and Engineering, 2019, 29(04): 24-29.

Figures/Tables 8

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References 24

[1]	HAYES M H B, MACCARTHY P, MALCOLM R L , et al. Humic substances II. In search of structure.[M] // Humic substances II : in search of structure J Wiley, 1989.
[2]	郝晓地, 周鹏, 曹亚莉 . 污水处理中腐殖质的来源及其演变过程[J]. 环境工程学报, 2017,11(1):1-11.
[3]	ASGHARIAN F, KHOSRAVI-NIKOU M R, ANVARIPOURB , et al. Electrocoagulation and ultrasonic removal of humic acid from wastewater[J]. Environmental Progress & Sustainable Energy, 2017,36(3):822-829.
[4]	ATEIA M, Ran J, FUJII M , et al. The relationship between molecular composition and fluorescence properties of humic substances[J]. International Journal of Environmental Science & Technology, 2017,14(4).
[5]	ILLES E, TOMBACZ E . The role of variable surface charge and surface complexation in the adsorption of humic acid on magnetite[J]. Colloids & Surfaces A Physicochemical & Engineering Aspects, 2003,230(1-3):99-109.
[6]	LV J, ZHANG S, WANG S , et al. Molecular-scale investigation with ESI-FT-ICR-MS on fractionation of dissolved organic matter induced by adsorption on iron oxyhydroxides[J]. Environmental science & technology, 2016,50(5):2328-2336.
[7]	RAO G, ZHANG Q, ZHAO H , et al. Novel titanium dioxide/iron (III) oxide/graphene oxide photocatalytic membrane for enhanced humic acid removal from water[J]. Chemical Engineering Journal, 2016,302:633-640.
[8]	SPOSITO G . The surface chemistry of soils[J]. 1984, 44(C3):C3-159-C3-162.
[9]	LI Z, LOWRY G V, FAN J , et al. High molecular weight components of natural organic matter preferentially adsorb onto nanoscale zero valent iron and magnetite[J]. Science of the Total Environment, 2018,628:177-185.
[10]	IANOS R, PACURARIU C, MUNTEAN S G , et al. Combustion synjournal of iron oxide/carbon nanocomposites, efficient adsorbents for anionic and cationic dyes removal from wastewaters[J]. Journal of Alloys and Compounds, 2018,741:1235-1246.
[11]	WANG Z, SHEN X, JING M , et al. Enhanced arsenic removal from drinking water by FeOOH/γ-Al₂O₃ granules[J]. Journal of Alloys and Compounds, 2018,735:1620-1628.
[12]	RAHMAN M S, WHALEN M, GAGNON G A . Adsorption of dissolved organic matter (DOM) onto the synthetic iron pipe corrosion scales (goethite and magnetite): Effect of pH[J]. Chemical engineering journal, 2013,234:149-157.
[13]	KASPRZYK-HORDERN B . Chemistry of alumina, reactions in aqueous solution and its application in water treatment[J]. Advances in colloid and interface science, 2004,110(1-2):19.
[14]	许建红, 高乃云, 唐玉霖 , 等. 浅析水合氧化铁的研究进展[J]. 水处理技术, 2011,37(8):22-25.
[15]	GU C, KARTHIKEYAN K G . Sorption of the antimicrobial ciprofloxacin to aluminum and iron hydrous oxides[J]. Environmental science & technology, 2005,39(23):9166-9173.
[16]	Wang K, Li W, Gong X J , et al. Spectral study of dissolved organic matter in biosolid during the composting process using inorganic bulking agent: UV-vis, GPC, FTIR and EEM[J]. International Biodeterioration & Biodegradation, 2013,85(7):617-623.
[17]	PIFER A D, FAIREY J L . Improving on SUVA 254, using fluorescence-PARAFAC analysis and asymmetric flow-field flow fractionation for assessing disinfection byproduct formation and control[J]. Water Research, 2012,46(9):2927. doi: 10.1016/j.watres.2012.03.002
[18]	FUENTES M, GONZALEZ-GAITANO G, JOSE M A GARCIA-MINA . The usefulness of UV-visible and fluorescence spectroscopies to study the chemical nature of humic substances from soils and composts[J]. Organic Geochemistry, 2006,37(12):1949-1959.
[19]	PEURAVUORI J, PIHLAJA K . Molecular size distribution and spectroscopic properties of aquatic humic substances[J]. Analytica Chimica Acta, 1997,337(2):133-149.
[20]	SANCHEZ N P, SKERIOTIS A T, MILLER C M . A PARAFAC-based long-term assessment of DOM in a multi-coagulant drinking water treatment scheme.[J]. Environmental Science & Technology, 2014,48(3):1582-91.
[21]	CHEN W, PAUL WESTERHOFF, AND J A L , et al. Fluorescence Excitation-Emission Matrix Regional Integration to Quantify Spectra for Dissolved Organic Matter[J]. Environmental Science & Technology, 2003,37(24):5701.
[22]	SANCHEZ N P, SKERIOTIS A T, MILLER C M . Assessment of dissolved organic matter fluorescence PARAFAC components before and after coagulation-filtration in a full scale water treatment plant[J]. Water Research, 2013,47(4):1679-90.
[23]	YU H, QU F, SUN L , et al. Relationship between soluble microbial products (SMP) and effluent organic matter (EfOM): characterized by fluorescence excitation emission matrix coupled with parallel factor analysis[J]. Chemosphere, 2015,121(4):101-9.
[24]	马宏瑞, 郝永永, 王晴 , 等. 臭氧及电化学氧化处理制革生化尾水比较研究[J]. 中国皮革, 2018,47(02):40-47+51.

参数	DOC/(mg/L)	UV₂₅₄	SUVA₂₅₄	E₂₅₃/E₂₀₃	E₂₅₄/E₃₆₅
0 h	73.80	2.04	2.76	0.06	7.54
1 h	55.28	1.47	2.66	0.056	8.22
2 h	42.66	0.91	2.13	0.038	8.96
4 h	39.12	0.53	1.35	0.024	10.01
8 h	32.07	0.14	0.44	0.007	6.57

Adsorption of Dissolved Organic Matter in Biochemical Tail Water by Fe(III)-Al₂O₃

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