氟硅改性无溶剂聚氨酯涂层的制备及性能研究

doi:10.19677/j.issn.1004-7964.2023.01.003

Leather Science and Engineering ›› 2023, Vol. 33 ›› Issue (1): 15-20.doi: 10.19677/j.issn.1004-7964.2023.01.003

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Preparation and Property of Fluorine-Silicone Modified Solvent-Free Polyurethane Coating

SUN Zhe¹, REN Song¹, FANG Jian¹, FAN Haojun^2,*, GAO Qiang²

1. College of Textile and Clothing Engineering, Soochow University, Suzhou 215123, China;
2. College of Biomass Science and Engineering, Sichuan University, Chengdu 610065, China

Received:2022-05-31 Published:2023-02-01 Online:2023-01-04

Abstract

Abstract: A kind of fluorine-silicone modifier (PSF) was synthesized by grafting hexafluorobutyl acrylate onto polydimethylhydrosiloxane via hydrosilylation reaction, and then used for the modification of solvent-free two-component polyurethane. The synthesis process of the modifier was optimized, and the surface morphology, hydrophobicity and abrasion resistance of the PSF modified polyurethane coatings were investigated. Results showed that the optimum reaction temperature, time and catalyst loading were 120 ℃, 12 h and 30 mg/kg, respectively. In this condition, the grafting ratio could reach 89%. Results of surface morphology and elemental analysis showed that the fluorine and silicon elements were well dispersed in the polyurethane coating. The surface roughness and water contact angle (WCA) of the coating exhibited an obvious increase with the addition of PSF. When the PSF loading was 7.5%, the coating’s WCA could reach 118.3°. Results of abrasion resistance test presented that the coating’s abrasion resistance first increased and then decreased with the increase of PSF content, and the best abrasion resistance was achieved with the PSF loading of 2.5%.

Key words: fluorine-silicone modification, solvent-free polyurethane, coating, hydrophobicity, abrasion resistance

CLC Number:

TS529.5

SUN Zhe, REN Song, FANG Jian, FAN Haojun, GAO Qiang. Preparation and Property of Fluorine-Silicone Modified Solvent-Free Polyurethane Coating[J]. Leather Science and Engineering, 2023, 33(1): 15-20.

References

[1] 范浩军,袁继新.人造革/合成革材料及工艺学[M].北京:中国轻工业出版社,2010.
[2] 徐一剡,章建剑,王旭.水性生态合成革涂饰剂的制备及应用研究[J].皮革制作与环保科技,2022,3(2):7-9.
[3] 张哲. 合成革用水性聚氨酯的制备及工程技术应用研究[D].西安:陕西科技大学,2015.
[4] 冯见艳,王学川,张哲,等.聚氨酯合成革绿色清洁化生产发展趋势分析与探讨[J].皮革科学与工程,2018,28(1):26-30.
[5] Zhang P,Zhou Y,Su H,et al.Hydroxyl-decorated ammonium polyphosphate as flame retardant reinforcing agent in solvent-free two-component polyurethane[J].Polymer International,2017,66(11):1598-1609.
[6] 高静. 合成革用无溶剂聚氨酯面层树脂的制备与应用[D].西安:陕西科技大学,2017.
[7] 蒋文佳,余冬梅,王小君,等.涂层用无溶剂双组份聚氨酯的制备[J].皮革科学与工程,2017,27(6):40-43.
[8] Lv D,Fang N,Zhang W.A PDMS modified polyurethane/Ag composite coating with super-hydrophobicity and low infrared emissivity[J].Infrared Physics&Technology,2020,108:103351.
[9] Król B,Król P,Byczyński L,et al.Methods of increasing hydrophobicity of polyurethane materials:Important applications of coatings with low surface free energy[J].Colloid and Polymer Science,2017,295(12):2309-2321.
[10] Sui Z,Li Y,Guo Z,et al.Preparation and properties of polysiloxane modified fluorine-containing waterborne polyurethane emulsion[J].Progress in Organic Coatings,2022,166:106783.
[11] 张怀文,杜淼,王楠,等.拒水型有机硅改性聚氨酯嵌段共聚物的合成与表征[J].高分子学报,2013(1):63-69.
[12] 陈精华,刘伟区,宣宜宁,等.有机硅改性聚氨酯弹性体材料的研究[J].聚氨酯工业,2004,19(1):12-15.
[13] Zhang W,Jiang S,Lv D.Fabrication and characterization of a PDMS modified polyurethane/Al composite coating with super-hydrophobicity and low infrared emissivity[J].Progress in Organic Coatings,2020,143:105622.
[14] Wen J,Sun Z,Fan H,et al.Synthesis and characterization of a novel fluorinated waterborne polyurethane[J].Progress in Organic Coatings,2019,131:291-300.
[15] Huang Z,Nazifi S,Cheng K,et al.Scalable inter-diffused zwitterionic polyurethanes for durable antibacterial coatings[J].Chemical Engineering Journal,2021,422:130085.
[16] Sun Q,Li H,Xian C,et al.Mimetic marine antifouling films based on fluorine-containing polymethacrylates[J].Applied Surface Science,2015,344:17-26.
[17] Park J M,Lee Y H,Park H,et al.Preparation and properties of UV-curable fluorinated polyurethane acrylates[J].Journal of Applied Polymer Science,2014,131(16):1107-1117.
[18] 李亚萍,隋智慧,郭制安,等.有机氟硅改性水性聚氨酯的合成及应用[J].热固性树脂,2021,36(4):15-19.
[19] 左一杰,李凤艳,蔚红建,等.氟硅复合改性水性聚氨酯的制备及性能研究[J].现代化工,2021,41(1):123-127.
[20] 郑桂凯,陆明,芮小平.有机氟、硅改性水性聚氨酯的研究进展[J].涂料工业,2018,48(7):79-87.
[21] Liu H,Fu B,Li Y,et al.Antigraffiti polyurethane coating containing fluorocarbon side chains grafted polymethylsiloxane[J].Journal of Coatings Technology and Research,2013,10(3):361-369.
[22] 郭松,王梓丞,但年华,等.有机硅改性水性聚氨酯成膜剂的研究[J].中国皮革,2013,42(5):42-44.

Preparation and Property of Fluorine-Silicone Modified Solvent-Free Polyurethane Coating

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