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木质磺酸钠基荧光碳量子点构筑皮革防伪层

Construction of Leather Anti-Counterfeiting Layer by Fluorescent Carbon Quantum Dots Prepared from Sodium Lignosulfonate

  • 摘要: 以木质磺酸钠(SL)为碳源,邻苯二胺(OPDA)为氮源,通过水热法制备得到了氮掺杂的荧光碳量子点(N-CQDs)。它具有类球形的微观形貌和良好的水溶性,在254 nm和365 nm紫外灯下分别发射出蓝紫色和青绿色的荧光,表现出双通道荧光发射性能。将N-CQDs与阳离子型皮革涂饰剂以1∶4的体积比共混后得到荧光乳液(N-CW1-4),表现出良好的稳定性和分散性,平均水合粒径仅有42.3 nm,且同样表现出双通道荧光发射性能。N-CW1-4作为荧光防伪涂层被成功应用于皮革防伪,其构建的防伪点阵图案不论是在高温(65 ℃)、低温(-21 ℃)还是连续紫外辐射(365 nm)下均表现出优异的荧光稳定性。此外,在模拟淋雨和滚筒洗衣场景内,该防伪点阵涂层仍然具有牢靠的稳定性,并且N-CW1-4可被扩展到多种颜色皮革的防伪涂饰。研究为皮革防伪提供了新的方法和策略,对皮革市场的安全和良性发展具有积极意义。

     

    Abstract: N-Doped fluorescent carbon quantum dots (N-CQDs) were prepared by hydrothermal method with sodium lignosulfonate as carbon source and O-phenylenediamine as nitrogen source. N-CQDs exhibited a spherical micro-morphology and good water-solubility, and could emit blue-violet and cyan-green fluorescence under 254 nm and 365 nm ultraviolet (UV) light, respectively, indicating the dual-channel fluorescence emission properties. A fluorescent emulsion (N-CW1-4) was further prepared by blending N-CQDs with cationic leather finishing agent at a volume ratio of 1∶4. N-CW1-4 possessed good stability and dispersion, and its average hydrated particle size was only 42.3 nm. Meanwhile, it could also exhibit the dual-channel fluorescence emission properties. N- CW1- 4 as a fluorescent anti- counterfeiting coating was successfully applied in the field of leather anti-counterfeiting. The resulting anti-counterfeiting lattice pattern exhibited excellent fluorescence stability at high temperature (65 ℃), low temperature (-21 ℃), and continuous UV radiation (365 nm). In addition, the fluorescent anti-counterfeiting coating was still stable in the simulated rain and roller washing scenes. N-CW1-4 could also be extended to the anti-counterfeiting coatings with various colors of leather. This work provides a new method and strategy for leather anti-counterfeiting and has positive significance for the safety and benign development of leather market.

     

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