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基于干燥过程规律的戊二醛鞣革整理实践

Practical Experience Practice of Glutaraldehyde Tanned Leather based on the Drying Process Laws

  • 摘要: 干整理是将湿态坯革脱水并辅以机械加工处理过程。直接将含水量≥95%的坯革干燥至含水量14% ~16%,坯革易产生体积收缩,导致硬度增加,难以满足理想的使用性能。如何将坯革在“干燥脱水–纤维粘结–机械松散”的加工过程中获得良好定型、满足感官要求一直是制革的目标。已有的研究表明,铬鞣与植物鞣坯革的含水量与其弹性模量(E)之间存在相似的变化规律。为了达到既定的感官质量,湿态坯革的干整理可以按照该规律进行适应性的机械力调控。文章总结了当下常见干整理工序的操作参数,并对四种黄牛戊二醛鞣平纹革的干整理流程进行了描述,阐释了坯革含水量与机械加工之间的关系。

     

    Abstract: Dry finishing is a dehydrating process of wet crust leather supplemented with mechanical processing. If the wet crust leather with a moisture content of ≥ 95% is directly dried to a moisture content of 14%–16%, the crust leather is prone to volume shrinkage, resulting in an increase in hardness and making it difficult to meet the ideal performance requirements for use. How to achieve good shaping and meet sensory requirements of the crust leather during the processing of "drying and dehydration-fiber bonding-mechanical loosening" has always been the goal of leather making. Previous studies indicated that there was a common variation pattern between the moisture content and elastic modulus (E) of chrome-tanned or plant-tanned leather. In order to achieve the predetermined sensory quality, the dry finishing of wet crust leather can be adaptively regulated by mechanical force in accordance with this variation pattern. This article summarized the operation parameters of the common dry finishing processes at present, described the dry finishing procedures of four types of yellow cattle glutaraldehyde-tanned plain leather, and demonstrated the relationship between the moisture content of the crust leather and mechanical processing.

     

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