淀粉基吸水树脂后处理方式对其吸水性能的影响

doi:10.19677/j.issn.1004-7964.2023.03.004

皮革科学与工程 ›› 2023, Vol. 33 ›› Issue (3): 19-23.doi: 10.19677/j.issn.1004-7964.2023.03.004

淀粉基吸水树脂后处理方式对其吸水性能的影响

谭琼^1,2, 贾欣宇^1,2, 陈慧^1,2,*

1.四川大学轻工科学与工程学院,四川成都 610065;
2.四川大学制革清洁技术国家工程实验室,四川成都 610065

收稿日期:2022-09-09 出版日期:2023-06-01 上线日期:2023-05-17
通讯作者: *陈慧,女,博士,副教授,E-mail: chenh@scu.edu.cn。
作者简介:谭琼（1996-）,女,硕士研究生,研究方向：生物质材料及其改性。E-mail: tanqiong12@163.com。
基金资助:
四川省应用基础研究项目（2022NSFSC0351）

Effect of Post-Treatment Methods on the Water Absorbency of Starch-based Absorbent Polymers

TAN Qiong^1,2, Jia Xinyu^1,2, CHEN Hui^1,2,*

1. College of Biomass Science and Engineering, Sichuan University, Chengdu 610065, China;
2. National Engineering Laboratory for Clean Technology of Leather Manufacture, Sichuan University, Chengdu 610065, China

Received:2022-09-09 Published:2023-06-01 Online:2023-05-17

摘要/Abstract

摘要： 淀粉基吸水树脂因不同纯化和干燥后处理方式形成的不同微孔结构,是影响其吸水性能的关键。文章利用傅里叶变换红外光谱仪,X射线衍射仪,差示扫描量热分析仪和扫描电子显微镜对不同后处理方式的淀粉基吸水树脂的化学结构和性能进行表征。结果表明,后处理方式没有改变淀粉基吸水树脂的晶型结构和玻璃化转变温度;乙醇浸泡处理相比水提醇沉的淀粉基吸水树脂,外表层更加致密,孔洞更深;冷冻干燥相比热风干燥的淀粉基吸水树脂,微孔结构更加完整,孔径更小,孔分布更密集,孔隙率更高。乙醇浸泡-冷冻干燥后处理的淀粉基吸水树脂吸水倍率最高,浸泡吸水24 h,吸水倍率可达1320 g/g,因此乙醇浸泡-冷冻干燥是一种较好的后处理方式。

关键词: 淀粉基吸水树脂, 后处理方式, 吸水倍率

Abstract: Different microporous structures of starch-based absorbent polymers formed by using different post-processing methods such as purification and drying are the key factors affecting their water absorbency. The chemical structure and properties of the starch-based absorbent polymers post-treated with different methods were characterized by Fourier Transform Infrared Spectrometer, X-Ray Diffraction, Differential scanning calorimetry and Scanning Electron Microscopy techniques. The results showed that post-treatment methods did not change the crystal structures and glass transition temperatures of the starch-based absorbent polymers. Compared with the water extraction method, the ethanol soaking post-treatment could result in the starch-based absorbent polymer with the denser surface layer and the deeper pore structure; compared to the ones dried by hot air, the starch-based absorbent polymers obtained by the freeze drying method featured the more complete microporous structure, the smaller pore size, the denser pore distribution and the higher porosity. After ethanol soaking and freeze-drying treatment, the resulting starch-based absorbent polymers exhibited the highest water absorbency, and the water absorption rate could reach 1320 g/g soaking for 24 h. Thus, this treatment is an excellent post-treatment method.

Key words: starch-based absorbent polymer, post-processing method, water absorbency

中图分类号:

TQ322

谭琼, 贾欣宇, 陈慧. 淀粉基吸水树脂后处理方式对其吸水性能的影响[J]. 皮革科学与工程, 2023, 33(3): 19-23.

TAN Qiong, Jia Xinyu, CHEN Hui. Effect of Post-Treatment Methods on the Water Absorbency of Starch-based Absorbent Polymers[J]. Leather Science and Engineering, 2023, 33(3): 19-23.

参考文献

[1] Gupta A D, Rawat K P, Bhadauria V, et al.Recent trends in the application of modified starch in the adsorption of heavy metals from water: A review[J].Carbohydrate Polymers, 2021, 269: 117763.
[2] Asharuddin S M, Othman N, Altowayti W A H, et al.Recent advancement in starch modification and its application as water treatment agent[J].Environmental Technology & Innovation, 2021, 23: 101637.
[3] Qamruzzaman M, Ahmed F, Mondal M I H.An Overview on starch-based sustainable hydrogels: Potential applications and aspects[J].Journal of Polymers and the Environment , 2021, 30(1): 19-50.
[4] Supare K, Mahanwar P A.Starch-derived superabsorbent polymers in agriculture applications: an overview[J].Polymer Bulletin, 2021, 79(8): 5795-5824.
[5] 付渊,赵慧芳,庄紫微.淀粉基高吸水树脂对镍离子和锌离子的吸附研究[J].内蒙古石油化工,2020,46(8):13-15.
[6] 郑进宝,李琛.淀粉基包装材料疏水性改善研究进展[J].化工进展,2020,41(6):1-16.
[7] Tang X L, Pikal M J.Design of freeze-drying processes for pharmaceuticals: practical advice[J].Pharmaceutical Research, 2004, 21(2): 191-200.
[8] Krokida M K, Maroulis Z B.Effect of drying method on shrinkage and porosity[J].Drying Technology, 1997, 15(10): 2441-2458.
[9] Risbud M V, Hardikar A A, Bhat S V, et al.pH-sensitive freeze-dried chitosan-polyvinyl pyrrolidone hydrogels as controlled release system for antibiotic delivery[J].Journal of Controlled Release, 2000, 68(1): 23-30.
[10] An K J, Zhao D D, Wang Z F, et al.Comparison of different drying methods on Chinese ginger (Zingiber officinale Roscoe): Changes in volatiles, chemical profile, antioxidant properties, and microstructure[J].Food Chemistry, 2016, 197: 1292-1300.
[11] Milovanovic S, Jankovic-Castvan I, Ivanovic J, et al.Effect of starch xero and aerogels preparation on the supercritical CO₂ impregnation of thymol[J].Starch-Stärke, 2015, 67(1-2): 174-182.
[12] Broeckx G, Vandenheuvel D, Claes I J J, et al.Drying techniques of probiotic bacteria as an important step towards the development of novel pharmabiotics[J].International Journal of Pharmaceutics, 2016, 505(1-2): 303-318.
[13] Sampaio G L A, Pacheco S, Ribeiro A P O, et al.Encapsulations of a lycopene-rich watermelon concentrate in alginate and pectin beads: Characterization and stability[J].LWT-Food Science and Engineering, 2019, 116: 108589.
[14] 闵燕,谭琼,陈利维,等.NaOH溶液预处理马铃薯淀粉对其微观结构影响[J].皮革科学与工程,2022,32(4):20-24.
[15] 陈利维,陈慧,戴睿,等.碱溶解玉米淀粉制备高吸水性树脂[J].精细化工,2019,36(10):2109-2115.
[16] Chen LW, Zhu Y Y, Cui Y M, et al.Fabrication of starch-based high-performance adsorptive hydrogels using a novel effective pretreatment and adsorption for cationic methylene blue dye: Behavior and mechanism[J].Chemical Engineering Journal, 2021, 405: 126953.
[17] 李廷希,陈泉良,魏萌,等.淀粉接枝类高吸水树脂的合成研究[J].化学推进剂与高分子材料,2012,10(6):58-61+74.
[18] 任静,刘刚,欧全宏,等.淀粉的红外光谱及其二维相关红外光谱的分析鉴定[J].中国农学通报,2015,31(17):58-64.
[19] 吕昂,张俐娜,纤维素溶剂研究进展[J].高分子学报,2007(10):937-944.
[20] Xu Z, Fei Q Z, Zhang X Y.Synthesis of the starch grafting of superabsorbent and high oil-absorbing resin[J].Journal of Environmental Sciences, 2013, 25: S97-S10.
[21] 何珠莲,戴宇阳,陈慧.NaOH/甲酰胺/尿素溶剂体系对可溶性淀粉的溶解[J].皮革科学与工程,2021,31(6):21-26.
[22] 朱云燕,戴睿,陈慧.基于硫脲复合溶剂体系制备再生冷水可溶性淀粉[J].皮革科学与工程,2020,30(4):13-16+23.
[23] Hu J B, Cheng F, Lin Y, et al.Dissolution of starch inurea/NaOH aqueous solutions[J].Journal of Applied Polymer Science, 2016, 133(19): 43390.
[24] Athawale V D, Lele V.Thermal studies on granular maize starch and its graft copolymers with vinyl monomers[J].Starch-Stärke, 2000, 52(6-7): 205-213.
[25] Duarte M G, Brunnel D, Gil M H, et al.Microcapsules prepared from starch derivatives[J].Journal of Materials Science: Materials in Medicine, 1997, 8(5): 321-323.
[26] Zobel H F.Starch crystal transformations and their industrial importance[J].Starch-Stärke, 1988, 40(1): 1-7.
[27] Jane J, Craig S A S, Seib P A, et al.Characterization of granular cold water-soluble starch[J].Starch-Stärke, 1986, 38(8): 258-263.
[28] 洪雁,顾正彪.淀粉及变性淀粉颗粒形貌结构的研究[J].食品与发酵工业,2006,32(7):19.
[29] 万琪,李旭春,潘丙才.乙醇处理对树脂基纳米水合氧化铁结构及其除砷性能的影响[J].环境科学,2013,34(8):3151-3155.
[30] 舒心莹,孟宪生,潘英,等.乙醇梯度处理和树脂联用技术对白芍中白芍总苷的纯化研究[J].中药材,2010,33(11):1788-1791.
[31] 张帆,徐桂明,朱丽珺,等.水解对SL-g-P(AA-AM)/PVP半互穿高吸水树脂结构与性能的影响[J].精细化工,2022,39(9):1794-1804.
[32] 郑梅霞,肖荣凤,陈梅春,等.不同干燥方式对细菌纤维素复水性能的影响[J].福建农业学报,2021,36(12):1499-1505.
[33] 乔宇杭,王桂萍,钱石川,等.淀粉接枝丙烯酸高吸水树脂制备及性能[J].沈阳理工大学学报,2019,38(2):70-74.

淀粉基吸水树脂后处理方式对其吸水性能的影响

Effect of Post-Treatment Methods on the Water Absorbency of Starch-based Absorbent Polymers

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